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note
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Throughout this paper, the various features will be referred to by their nominal monomer charge states. It is not intended to imply that these species are pure monomers or even contain the monomer, which is clearly impossible for the -5/2 charge state. However, it does avoid both awkward language and ambiguity in identifying the mass spectral features we are discussing.
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note
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A word of caution must be given, however, for data at these lowest injection energies. Below 30 or 40 eV injection energy, discrimination against larger species can occur. This happens due to collisional scattering of the species trying to enter the cell from the ion funnel; the larger the cross section of the species, the more the scatter and the lower the transmission. Hence, while the trend toward higher-order oligomers most probably continues below 60 eV, the quantitative distribution of components in the peaks becomes less certain. This is unfortunate because, as the injection energy is lowered, less collisional dissociation or conformational annealing occurs, and hence, a more accurate picture emerges of the oligomer distribution in solution. On balance, considering all of the evidence, the nominal -2 monomer peak being sprayed from solution is dominated by dimer and trimer.
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