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For reviews and key papers on ring-closing metathesis and cross-metathesis, see: (a) A.K. Chatterjee, J.P. Morgan, M. Scholl, and R.H. Grubbs J. Am. Chem. Soc. 122 2000 3783
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M. Schuman, M. Trevitt, A. Redd, and V. Gouverneur Angew. Chem., Int. Ed. 39 2000 2491
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Schuman, M.1
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C.A. Slinn, C. Edlin, A.J. Redgrave, S.L. Hind, S.P. Nolan, and V. Gouverneur Org. Biomol. Chem. 1 2003 3820
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Slinn, C.A.1
Edlin, C.2
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Gouverneur, V.6
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K. Takaki, G. Koshoji, K. Komeyana, M. Takeda, T. Shishido, A. Kitanin, and K. Takeshira J. Org. Chem. 68 2003 6554 and references therein
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Kitanin, A.6
Takeshira, K.7
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0029025148
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For unsymmetical di- and trialkenyl phosphine oxides, see: (d) J.-F. Gnon, K. Pilard, A.-C. Tantaoui, J.-M. Gaumont, and Denis Tetrahedron Lett. 36 1995 4421
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Gnon, J.-F.1
Pilard, K.2
Tantaoui, A.-C.3
Gaumont, J.-M.4
Denis5
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13644255703
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B.A. Trofimov, N.K. Gusarova, S.F. Malysheva, V.I. Dmitriev, T.N. Rakhmatulina, and M.G. Voronkov Phosphorus, Sulfur Silicon Relat. Elem. 51/52 1990 713
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Dmitriev, V.I.4
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Voronkov, M.G.6
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21
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85030820043
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Abstracts of Papers, Boston, MA, USA, August 18-22, 2002, ORGN-216.
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To the best of our knowledge, there are no examples in the literature of desymmetrization of prochiral substrates by direct cross-metathesis leading to racemic or enantioenriched products. For an abstract presenting the concept, see: (a) Goldberg, S. D.; Ward, D. W.; Berlin, J. M.; Toste, F. D.; Grubbs, R.H. Abstracts of Papers, 224th ACS National Meeting, Boston, MA, USA, August 18-22, 2002 (2002), ORGN-216.
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224th ACS National Meeting
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Goldberg, S.D.1
Ward, D.W.2
Berlin, J.M.3
Toste, F.D.4
Grubbs, R.H.5
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22
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3342927719
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For a paper reporting on a 'net' cross-metathesis according to an in situ ARCM/ring opening process leading to enantioenriched products, see: (b) A. Jernelius, R.R. Schrock, and A.H. Hoveyda Tetrahedron 60 2004 7345
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Tetrahedron
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Jernelius, A.1
Schrock, R.R.2
Hoveyda, A.H.3
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26
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85030824727
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see Ref. 1(b).
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For the definition of types I-IV olefins, see Ref. 1(b).
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