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Of the substrates in Tables 1 and 2, similar thermal reaction was observed for phenylacetylene (2d) and α-methylstyrene in refluxing THF, giving rise to 3d (80%, E/Z = 21/79) and 8a (40%), respectively. However, these reactions did not occur at room temperature.
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43
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n prepared from 1 and 14; unpublished results.
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