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Volumn 7, Issue 1, 2005, Pages 10-13

Accelerating the living polymerization of 2-nonyl-2-oxazoline by implementing a microwave synthesizer into a high-throughput experimentation workflow

Author keywords

[No Author keywords available]

Indexed keywords

2 NONYL 2 OXAZOLINE; OXAZOLINE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 13544277565     PISSN: 15204766     EISSN: None     Source Type: Journal    
DOI: 10.1021/cc049846f     Document Type: Article
Times cited : (75)

References (33)
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    • (1999) Angew. Chem., Int. Ed. , vol.38 , pp. 2494-2532
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    • 0037421895 scopus 로고    scopus 로고
    • Adams, D. Nature 2003, 421, 571-572.
    • (2003) Nature , vol.421 , pp. 571-572
    • Adams, D.1
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    • 0000263347 scopus 로고    scopus 로고
    • Kuhnert, N. Angew. Chem. 2002, 114, 1943-1946; Angew. Chem., Int. Ed. 2002, 41, 1863-1866.
    • (2002) Angew. Chem. , vol.114 , pp. 1943-1946
    • Kuhnert, N.1
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    • 0037013893 scopus 로고    scopus 로고
    • Kuhnert, N. Angew. Chem. 2002, 114, 1943-1946; Angew. Chem., Int. Ed. 2002, 41, 1863-1866.
    • (2002) Angew. Chem., Int. Ed. , vol.41 , pp. 1863-1866
  • 26
    • 13544267564 scopus 로고    scopus 로고
    • note
    • During all described experiments, the microwave synthesizer was operated in temperature control mode, meaning that the applied power (maximum 300 W) was automatically adjusted to reach and maintain the set temperature. After the programmed reaction time, the vial was actively cooled by a pressurized nitrogen flow. The temperature inside the reaction vial was monitored by an IR temperature sensor; pressure was monitored from the bowing of the septum on top of the reaction vial.
  • 29
    • 13544266331 scopus 로고    scopus 로고
    • In preparation
    • Full details regarding the kinetic investigations in acetonitrile will be published in a forthcoming full paper: Wiesbrock, F.; Hoogenboom, R.; Leenen, M. A. M.; Schubert, U. S. In preparation.
    • Wiesbrock, F.1    Hoogenboom, R.2    Leenen, M.A.M.3    Schubert, U.S.4
  • 32
    • 13544263351 scopus 로고    scopus 로고
    • note
    • To reach temperatures higher than 140°C, larger polymerization volumes were required to ensure that at least 0.5 mL of liquid phase, which is required for an optimal microwave absorption in the utilized microwave synthesizer, was present in the microwave vials.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.