Parallel Kinetic Investigation of 2-Oxazoline Polymerizations with Different Initiators as Basis for Designed Copolymer Synthesis

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 42, Issue 8, 2004, Pages 1830-1840

  Hoogenboom, Richard ^a   Fijten, Martin W M ^a   Schubert, Ulrich S ^a  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

Automated synthesis; Cationic polymerization; High throughput experimentation; Living polymerization; Poly(2 oxazoline); Ring opening polymerization

Indexed keywords

CATALYSIS; CATIONIC POLYMERIZATION; COMPOSITION; ENZYMES; GAS CHROMATOGRAPHY; GEL PERMEATION CHROMATOGRAPHY; HYDROGELS; HYDROPHOBICITY; INITIATORS (CHEMICAL); LIVING POLYMERIZATION; MICELLES; MONOMERS; RING OPENING POLYMERIZATION; SYNTHESIS (CHEMICAL);

AUTOMATED SYNTHESIS; HIGH-THROUGHPUT EXPERIMENTATION; PARALLEL KINETIC INVESTIGATION; POLY(2-OXAZOLINE);

COPOLYMERS;

POLYMER SCIENCE;

EID: 1942441445     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.20024     Document Type: Article

References (42)

1. Tomalia, D. A.; Sheetz, D. P. J Polym Sci Part A-1: Polym Chem 1966, 4, 2253-2265.
2. Seeliger, W.; Aufderhaar, E.; Diepers, W.; Feinauer, R.; Nehring, R.; Thier, W.; Hellmann, H. Angew Chem 1966, 20, 913-927.
3. Seeliger, W.; Aufderhaar, E.; Diepers, W.; Feinauer, R.; Nehring, R.; Thier, W.; Hellmann, H. Angew Chem Int Ed Engl 1966, 5, 875-889.
4. Aoi, K.; Okada, M. Prog Polym Sci 1996, 21, 151-208.
5. Lichkus, A. M.; Painter, P. C.; Coleman, M. M. Macromolecules 1988, 21, 2636-2641.
6. Webster, O. W. Science 1991, 496, 387-893.
7. Kobayashi, S.; Igarashi, T.; Moriuehi, Y.; Saegusa, T. Macromolecules 1986, 19, 535-541.
8. Jin, R.-H. Adv Mater 2002, 14, 889-892.
9. Persigehl, P.; Jordan, R.; Nuyken, O. Macromolecules 2000, 33, 6977-6981.
10. Nuyken, O.; Persigehl, P.; Weberskirch, R. Macromol Symp 2002, 177, 163-173.
11. Miyamoto, M.; Naka, K.; Shiozaki, M.; Chujo, Y.; Saegusa, T. Macromolecules 1990, 23, 3201-3205.
12. Naka, K.; Ohki, A.; Maeda, S. Chem Lett 1991, 1303-1306.
13. Chujo, Y.; Sada, K.; Matsumoto, K.; Saegusa, T. Macromolecules 1990, 23, 1234-1237.
14. Chujo, Y.; Sada, K.; Saegusa, T. Macromolecules 1993, 26, 6315-6319.
15. Hochwimmer, G.; Nuyken, O.; Schubert, U. S. Macromol Rapid Commun 1998, 19, 309-313.
16. Heller, M.; Schubert, U. S. Macromol Symp 2002, 177, 87-96.
17. McAlvin, J. E.; Scott, S. B.; Fraser, C. L. Macromolecules 2000, 33, 6953-6964.
18. Hoogenboom, R.; Fijten, M. W. M.; Meier, M. A. R.; Schubert, U. S. Macromol Rapid Commun 2003, 24, 92-97.
19. Cai, G.; Litt, M. H. J Polym Sci Part A: Polym Chem 1989, 27, 3603-3618.
20. Liu, Q.; Konas, M.; Riffle, J. S. Macromolecules 1993, 26, 5572-5576.
21. Dworak, A. Macromol Chem Phys 1998, 199, 1843-1849.
22. Hoogenboom, R.; Fijten, M. W. M.; Brändli, C.; Schroer, J.; Schubert, U. S. Macromol Rapid Commun 2003, 24, 98-103.
23. Saegusa, T.; Ikeda, H. Macromolecules 1973, 6, 808-811.
24. Saegusa, T.; Ikeda, H.; Fujii, H. Macromolecules 1972, 5, 359-362.
25. Saegusa, T.; Ikeda, H.; Fujii, H. Macromolecules 1973, 6, 315-319.
26. Saegusa, T.; Kobayashi, S.; Yamada, A. Makromol Chem 1976, 177, 2271-2283.
27. Liu, Q.; Konas, M.; Riffle, J. S. Macromolecules 1993, 26, 5572-5576.
28. Dworak, A. Macromol Chem Phys 1998, 199, 1843-1849.
29. Guis, C.; Cheradame, H. Eur Polym J 2000, 36, 2581-2590.
30. Reviews on combinatorial polymer research see: Jandeleit, B.; Schaefer, D. J.; Powers, T. S.; Turner, H. W.; Weinberg, W. H. Angew Chem 1999, 111, 2648-2689.
31. Reviews on combinatorial polymer research see: Jandeleit, B.; Schaefer, D. J.; Powers, T. S.; Turner, H. W.; Weinberg, W. H. Angew Chem Int Ed Engl 1999, 38, 2494-2532.
32. Reviews on combinatorial polymer research see: Hoogenboom, R.; Meier, M. A. R.; Schubert, U. S. Macromol Rapid Commun 2003, 24, 15-32.
33. Tomalia, D. A.; Sheetz, D. P. J Polym Sci Part A-1: Polym Chem 1966, 4, 2253-2265.
34. Seeliger, W.; Aufderhaar, E.; Diepers, W.; Feinauer, R.; Nehring, R.; Their, W.; Hellmann, H. Angew Chem 1966, 20, 913-927.
35. Seeliger, W.; Aufderhaar, E.; Diepers, W.; Feinauer, R.; Nehring, R.; Their, W.; Hellmann, H. Angew Chem Int Ed Engl 1966, 5, 875-889.
36. Aoi, K.; Okada, M. Prog Polym Sci 1996, 21, 151-208.
37. For pictures of the automated synthesizer and a detailed discussion of the high-throughput approach in poly(2-oxazoline) research, see: ref. 18.
38. For pictures of the automated synthesizer and a detailed discussion of the high-throughput approach in poly(2-oxazoline) research, see: Hoogenboom, R.; Fijten, M. W. M.; Schubert, U. S. Polym Prepr (Am Chem Soc Div Polym Chem) 2003, 44, 775-776.
39. For pictures of the automated synthesizer and a detailed discussion of the high-throughput approach in poly(2-oxazoline) research, see: Hoogenboom, R.; Schubert, U. S. J Polym Sci Part A: Polym Chem 2003, 41, 2425-2434.
40. Litt, M.; Levy, A.; Herz, J. J Macromol Sci Chem 1975, 5, 703-727.
41. The [M]/[I] ratios were calculated from the initial concentration of reagents and the conversion obtained with GC.
42. Kobayashi, S.; Tokuzawa, T.; Saegusa, T. Macromolecules 1982, 15, 707-710.