Preparation, characterization and electrochemical and X-ray structural studies of new conjugated 1,1′-ferrocenediyl-ended [CpFe-arylhydrazone] + salts

New Journal of Chemistry

Volumn 28, Issue 1, 2004, Pages 134-144

  Manzur, Carolina ^a   Zúñiga, César ^a   Millán, Lorena ^a   Fuentealba, Mauricio ^a   Mata, Jose A ^b   Hamon, Jean René ^c   Carrillo, David ^a  

^a PONTIFICIA UNIVERSIDAD CATÓLICA DE VALPARAÍSO   (Chile)

^b UNIVERSITAT JAUME I   (Spain)

^c Institut de Physique de Rennes   (France)

Author keywords

[No Author keywords available]

Indexed keywords

1,1' FERROCENEDICARBOXALDEHYDE; CARBON; CATION; HYDRAZONE DERIVATIVE; IRON DERIVATIVE; LIGAND; NITROGEN; ORGANOMETALLIC COMPOUND; SODIUM CHLORIDE; UNCLASSIFIED DRUG;

ARTICLE; ARYLATION; ATOM; CHEMICAL BOND; COMPLEX FORMATION; CONJUGATION; CORRELATION ANALYSIS; CROSS LINKING; CRYSTAL STRUCTURE; ELECTROCHEMISTRY; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; MOLECULAR MECHANICS; POLYMERIZATION; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; SYSTEM ANALYSIS; TRANS ISOMER; X RAY ANALYSIS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 1242343826     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: 10.1039/b308626g     Document Type: Article

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68. For neutral chromophores see, for example: (a) J. Mata, S. Uriel, E. Peris, R. Llusar, S. Houbrechts and A. Persoons, J. Organomet. Chem., 1998, 562, 197; (b) G. G. A. Balavoine, J.-C. Daran, G. Iftime, P. G. Lacroix, E. Manoury, J. A. Delaire, I. Maltey-Fanton, K. Nakatani and S. Di Bella, Organometallics, 1999, 18, 21; (c) J. A. Mata, E. Falomir, R. Llusar and E. Peris, J. Organomet. Chem., 2000, 616, 80; (d) J. A. Mata, S. Uriel, R. Llusar and E. Peris, Organometallics, 2000, 19, 3797; (e) J. A. Mata, E. Peris, I. Asselberghs, R. Van-Boxel and A. Persoons, New J. Chem., 2001, 25, 299; (f) I. Janowska, J. Zakrzewski, K. Nakatani, J. A. Delaire, M. Palusiak, M. Walak and H. Scholl, J. Organomet. Chem., 2003, 675, 35.
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74. For cationic chromophores see, for example: (a) V. Alain, A. Fort, M. Barzoukas, C.-T. Chen, M. Blanchard-Desce, S. R. Marder and J. W. Perry, Inorg. Chim. Acta, 1996, 242, 43; (b) T. Farrell, T. Meyer-Friedrichsen, M. Malessa, D. Haase, W. Saak, I. Asselberghs, K. Wostyn, K. Clays, A. Persoons, J. Heck and A. R. Manning, J. Chem. Soc., Dalton Trans., 2001, 29; (c) H. Wong, T. Meyer-Friedrichsen, T. Farrell, C. Mecker and J. Heck, Eur. J. Inorg. Chem., 2000, 631; (d) B. J. Coe, L. A. Jones, J. A. Harris, B. S. Brunschwig, I. Asselberghs, K. Clays and A. Persoons, J. Am. Chem. Soc., 2003, 125, 862.
75. For cationic chromophores see, for example: (a) V. Alain, A. Fort, M. Barzoukas, C.-T. Chen, M. Blanchard-Desce, S. R. Marder and J. W. Perry, Inorg. Chim. Acta, 1996, 242, 43; (b) T. Farrell, T. Meyer-Friedrichsen, M. Malessa, D. Haase, W. Saak, I. Asselberghs, K. Wostyn, K. Clays, A. Persoons, J. Heck and A. R. Manning, J. Chem. Soc., Dalton Trans., 2001, 29; (c) H. Wong, T. Meyer-Friedrichsen, T. Farrell, C. Mecker and J. Heck, Eur. J. Inorg. Chem., 2000, 631; (d) B. J. Coe, L. A. Jones, J. A. Harris, B. S. Brunschwig, I. Asselberghs, K. Clays and A. Persoons, J. Am. Chem. Soc., 2003, 125, 862.
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82. P. Zanello, in Ferrocenes: Homogenous Catalysis, Organic Synthesis, Materials Science, eds. A. Togni and T. Hayashi, Wiley-VCH, Weinheim, 1995, ch. 7, pp. 317-430.
83. The redox potentials of compounds 11-20 and those of their counterparts prepared in ref. 13b are compared relative to the ferrocene/ferricinium couple used in both cases as internal reference.
84. 4R′)] can be easily formed by deprotonation in the electrochemical medium. No attempts were made to characterize their corresponding non-deprotonated precursors 11-20 by CV.
85. - (ref. 46). Its integrated area is twice that of the wave at -2.44 V.
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