Highly unusual effects of π-conjugation extension on the molecular linear and quadratic nonlinear optical properties of ruthenium(II) ammine complexes

Journal of the American Chemical Society

Volumn 125, Issue 4, 2003, Pages 862-863

  Coe, Benjamin J ^a   Jones, Lathe A ^a   Harris, James A ^a   Brunschwig, Bruce S ^b   Asselberghs, Inge ^c   Clays, Koen ^c   Persoons, André ^c,d  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b BROOKHAVEN NATIONAL LABORATORY   (United States)

^c UNIVERSITY OF LEUVEN   (Belgium)

^d UNIVERSITY OF ARIZONA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; POLYENE; PYRIDINIUM DERIVATIVE; RUTHENIUM;

ABSORPTION SPECTROSCOPY; ARTICLE; CALCULATION; CHEMICAL REACTION; CHROMATOPHORE; CONJUGATION; HYPERPOLARIZATION; OXIDATION REDUCTION REACTION; POTENTIOMETRY; PREDICTION; TECHNIQUE;

EID: 0037471647     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028897i     Document Type: Article

References (26)

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24. 30 esu : -29.2 (0), -44.6 (1), -29.4 (2), -22.1 (3). Neither calculated MLCT maxima nor dipole parameters were quoted.
25. 6- salts of the free pyridyl ligands are as follows (nm. in MeCN): 264 (n = 0), 316 (n = 1), 356 (n = 2), 394 (n = 3).
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