First x-ray crystal structure of a bimetallic complex containing a rc-coordinated hydrazone:.[(TiB-Cp)Fe(Ti.MeOC6H4)-NHN=CH-TiB.C6HJFe(TiB.Cp)] PFe

Boletin de la Sociedad Chilena de Quimica

Volumn 46, Issue 4, 2001, Pages 409-413

  Manzur, Carolina ^a   Fuentealba, Mauricio ^a   Carrillo, David ^a   Boys, Daphne ^b   Hamon, Jean René ^c  

^a PONTIFICIA UNIVERSIDAD CATÓLICA DE VALPARAÍSO   (Chile)

^b DEPARTAMENTO DE FÍSICA   (Chile)

^c UNIVERSITÉ DE RENNES 1   (France)

Author keywords

Crystal structure; Ferrocene; Homobimetallic hydrazone organometallic hydrazone; Hydrazone; Iron mixed sandwich

Indexed keywords

EID: 0001381624     PISSN: 03661644     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (21)

1. Astruc, D., in "The Chemistry of the Metal-Carbon Bond", Vol. 4, F. R. Hartley, S.Patai Eds., Wiley, New York, p. 625(1987).
2. Abd-EI-Aziz, A. S., Bernardin, S., Coord. Chem. Rev., 203, 219 (2000).
3. Astruc, D., Tetrahedron Report N9157, Tetrahedron, 39, 4027 (1983).
4. Astruc, D., Top. Curr. Chem., 160, 47 (1991).
5. Astruc, D.,Acc. Chem. Res., 30, 383 (1997).
6. Astruc, D., Chem. Rev., 88,1189 (1988).
7. Hendrickson, W. A., Palazzotto, M. C., Photoinitiator Activity, Electrochemistry, and Spectroscopy of Cationic Organometallic Compounds, in "Photosensitive Metal-Organic Systems", C. Kutal, N. Serpone Eds., Advanced Chemistry Series 238, ACS, Washington, DC, p. 410 (1993).
8. a) Trujillo, H. A., Casado, C. M., Ruiz, J., Astruc, D., J.Am. Chem. Soc., 121, 5674 (1999).
9. b) Lambert, C., Gaschler, W., Zabel, M., Matschiner, R., Wortmann, R., J. Organomet. Chem., 592,109 (1999).
10. Manzur, C., Millân, L, Fuentealba, M., Hamon, J.-R., Carrillo, D., Tetrahedron Lett. 41,3615 (2000).
11. Manzur, C., Baeza, E., Millân, L, Fuentealba, M., Hamon, P., Hamon, J.-R., Boys, D., Carrillo, D., J. Organomet. Chem., 608,126 (2000).
12. Analytical data for [1]PF6-: m.p. 162 5C dec. C23H23F6Fe2N2OP (600.10): calcd. C, 46.03; H, 3.86; found C, 45.82; H, 3.78. UV/Vis (CH2CI2): Xmax (loge)= 240 (4.38), 309 (4.24), 344 (3.96, sh), 425 (3.46). IR (KBr): v 3337 cnr1 (m), v(NH); 3100 (w), v(CH); 2926, 2840 (w), v(CH); 1579 (s), v(C=N); .1254 (m), v(C-O); 852,844 (br, vs), v(PF6), 558 (m), o(P-F). 'H NMR [CD3COCD3,297 K]: 0= 4.08 (s, 3H, OCH3), 4.43 (s, 5H, CpFe), 4.64 (brs, 2H, C5H4), 4.94 (brs, 2H, C5H<), 5.13 (s, 5H, CpFe+), 6.28 (AB q, 4H, C6H, JH H = 6.9 Hz), 8.01 (s, 1 H, CH), 9.30 (br s, 1 H, NH).
13. Fillaut, J.-L, Boese, R., Astruc, D.,Synlett, 55 (1992).
14. Subramanian, S., Wang, L, Zaworotko, M., Organometallics, 12, 310 (1993).
15. Ishii, Y, Kawaguchi, M., Ishino, Y, Aoki, T., Hidai, M., Organometallics, 13, 5062 (1994).
16. Chavez, I., Alvarez-Carena, A., Molins, E., Roig, A., Maniukiewicz, W., Arancibia, A., Arancibia, V., Brand, H., Manrïquez, J. M., J. Organomet. Chem., 601,126 (2000).
17. Orpen, A. G., Brammer, L, Allen, F. H., Kennard, D., Watson, D. G., Taylor, R., J. Chem. Soc., Dalton Trans., S1 (1989).
18. Ruiz, J., Ogliaro, R, Saillard, J.-Y., Halet, J.-F., Varret, F., Astruc, D., J. Am. Chem. Soc., 20,11693 (1998).
19. Lynch, V. M., Thomas, S. N., Simonses, S. H., Piôrko, A., Sutherland, R. G., Acta Cryst., 042,1144(1986).
20. Saillard, J.-Y, Grandjean, D., Le Maux, P., Jaouen, G., Nouv. J. Chim., 5,153 (1981).
21. Sheldrick, G. M., 1997. SHELXL-97, Program forthe Refinement of Crystal Structures, University of Göttingen, Germany.