Inhibiting δ → π Isomerization of Aryloxide Ligands in Late Transition-Metal Complexes

Organometallics

Volumn 24, Issue 1, 2005, Pages 103-109

  Snelgrove, Jennifer L ^a   Conrad, Jay C ^a   Eelman, Melanie D ^a   Moriarty, Maeve M ^a   Yap, Glenn P A ^a   Fogg, Deryn E ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CHELATION; CHEMICAL BONDS; COMPLEXATION; CRYSTAL STRUCTURE; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE;

ELECTRON DEFICIENCY; LIGAND ARCHITECTURE; TRANSITION-METAL COMPLEXES;

TRANSITION METAL COMPOUNDS;

EID: 12344304487     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049394j     Document Type: Article

References (57)

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14. 4. See: (a) Cole-Hamilton, D. J.; Young, R. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1976, 1995. (b) Rosete, R. O.; Cole-Hamilton, D. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1979, 1618. (c) Christ, M. L.; Sabo-Etienne, S.; Chung, G.; Chaudret, B. Inorg. Chem. 1994, 33, 5316. (d) Cole-Hamilton, D. J.; Wilkinson, G. New J. Chem. 1977, 1, 141. (e) Bennett, M. A.; Matheson, T. W. J. Organomet. Chem. 1979, 175, 87. (f) Bücken, K.; Koelle, U.; Pasch, R.; Ganter, B. Organometallics 1996, 15, 3095. (g) Chaudret, B.; Xiaodong, H.; Huang, Y. J. Chem. Soc., Chem. Commun. 1989, 1844. (h) Koelle, U.; Wang, M. H.; Raabe, G. Organometallics 1991, 10, 2573.
15. 4. See: (a) Cole-Hamilton, D. J.; Young, R. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1976, 1995. (b) Rosete, R. O.; Cole-Hamilton, D. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1979, 1618. (c) Christ, M. L.; Sabo-Etienne, S.; Chung, G.; Chaudret, B. Inorg. Chem. 1994, 33, 5316. (d) Cole-Hamilton, D. J.; Wilkinson, G. New J. Chem. 1977, 1, 141. (e) Bennett, M. A.; Matheson, T. W. J. Organomet. Chem. 1979, 175, 87. (f) Bücken, K.; Koelle, U.; Pasch, R.; Ganter, B. Organometallics 1996, 15, 3095. (g) Chaudret, B.; Xiaodong, H.; Huang, Y. J. Chem. Soc., Chem. Commun. 1989, 1844. (h) Koelle, U.; Wang, M. H.; Raabe, G. Organometallics 1991, 10, 2573.
16. 4. See: (a) Cole-Hamilton, D. J.; Young, R. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1976, 1995. (b) Rosete, R. O.; Cole-Hamilton, D. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1979, 1618. (c) Christ, M. L.; Sabo-Etienne, S.; Chung, G.; Chaudret, B. Inorg. Chem. 1994, 33, 5316. (d) Cole-Hamilton, D. J.; Wilkinson, G. New J. Chem. 1977, 1, 141. (e) Bennett, M. A.; Matheson, T. W. J. Organomet. Chem. 1979, 175, 87. (f) Bücken, K.; Koelle, U.; Pasch, R.; Ganter, B. Organometallics 1996, 15, 3095. (g) Chaudret, B.; Xiaodong, H.; Huang, Y. J. Chem. Soc., Chem. Commun. 1989, 1844. (h) Koelle, U.; Wang, M. H.; Raabe, G. Organometallics 1991, 10, 2573.
17. 4. See: (a) Cole-Hamilton, D. J.; Young, R. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1976, 1995. (b) Rosete, R. O.; Cole-Hamilton, D. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1979, 1618. (c) Christ, M. L.; Sabo-Etienne, S.; Chung, G.; Chaudret, B. Inorg. Chem. 1994, 33, 5316. (d) Cole-Hamilton, D. J.; Wilkinson, G. New J. Chem. 1977, 1, 141. (e) Bennett, M. A.; Matheson, T. W. J. Organomet. Chem. 1979, 175, 87. (f) Bücken, K.; Koelle, U.; Pasch, R.; Ganter, B. Organometallics 1996, 15, 3095. (g) Chaudret, B.; Xiaodong, H.; Huang, Y. J. Chem. Soc., Chem. Commun. 1989, 1844. (h) Koelle, U.; Wang, M. H.; Raabe, G. Organometallics 1991, 10, 2573.
18. 4. See: (a) Cole-Hamilton, D. J.; Young, R. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1976, 1995. (b) Rosete, R. O.; Cole-Hamilton, D. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1979, 1618. (c) Christ, M. L.; Sabo-Etienne, S.; Chung, G.; Chaudret, B. Inorg. Chem. 1994, 33, 5316. (d) Cole-Hamilton, D. J.; Wilkinson, G. New J. Chem. 1977, 1, 141. (e) Bennett, M. A.; Matheson, T. W. J. Organomet. Chem. 1979, 175, 87. (f) Bücken, K.; Koelle, U.; Pasch, R.; Ganter, B. Organometallics 1996, 15, 3095. (g) Chaudret, B.; Xiaodong, H.; Huang, Y. J. Chem. Soc., Chem. Commun. 1989, 1844. (h) Koelle, U.; Wang, M. H.; Raabe, G. Organometallics 1991, 10, 2573.
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20. While of limited utility for olefin metathesis, such π-aryloxide species are of interest as catalysts for asymmetric Diels-Alder reactions (see: Faller, J. W.; D'Alliessi, D. G. Organometallics 2003, 22, 2749. F aller, J. W. ; Lavoie, A. R.; Grimmond, B. J. Organometallics 2002, 21, 1662) and are of potential relevance for nucleophilic phenol functionalization (see: Le Bras, J. ; Amouri, H.; Vaissermann, J. Inorg. Chem. 1998, 37, 5066 and references therein) or carbonylation (see: Dockter, D. W.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1996, 118, 4846. Rees, W. M.; Churchill, M. R.; Fettinger, J. C.; Atwood, J. D. Organometallics 1985, 4, 2179).
21. While of limited utility for olefin metathesis, such π-aryloxide species are of interest as catalysts for asymmetric Diels-Alder reactions (see: Faller, J. W.; D'Alliessi, D. G. Organometallics 2003, 22, 2749. F aller, J. W. ; Lavoie, A. R.; Grimmond, B. J. Organometallics 2002, 21, 1662) and are of potential relevance for nucleophilic phenol functionalization (see: Le Bras, J. ; Amouri, H.; Vaissermann, J. Inorg. Chem. 1998, 37, 5066 and references therein) or carbonylation (see: Dockter, D. W.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1996, 118, 4846. Rees, W. M.; Churchill, M. R.; Fettinger, J. C.; Atwood, J. D. Organometallics 1985, 4, 2179).
22. While of limited utility for olefin metathesis, such π-aryloxide species are of interest as catalysts for asymmetric Diels-Alder reactions (see: Faller, J. W.; D'Alliessi, D. G. Organometallics 2003, 22, 2749. F aller, J. W. ; Lavoie, A. R.; Grimmond, B. J. Organometallics 2002, 21, 1662) and are of potential relevance for nucleophilic phenol functionalization (see: Le Bras, J. ; Amouri, H.; Vaissermann, J. Inorg. Chem. 1998, 37, 5066 and references therein) or carbonylation (see: Dockter, D. W.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1996, 118, 4846. Rees, W. M.; Churchill, M. R.; Fettinger, J. C.; Atwood, J. D. Organometallics 1985, 4, 2179).
23. While of limited utility for olefin metathesis, such π-aryloxide species are of interest as catalysts for asymmetric Diels-Alder reactions (see: Faller, J. W.; D'Alliessi, D. G. Organometallics 2003, 22, 2749. F aller, J. W. ; Lavoie, A. R.; Grimmond, B. J. Organometallics 2002, 21, 1662) and are of potential relevance for nucleophilic phenol functionalization (see: Le Bras, J. ; Amouri, H.; Vaissermann, J. Inorg. Chem. 1998, 37, 5066 and references therein) or carbonylation (see: Dockter, D. W.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1996, 118, 4846. Rees, W. M.; Churchill, M. R.; Fettinger, J. C.; Atwood, J. D. Organometallics 1985, 4, 2179).
24. While of limited utility for olefin metathesis, such π-aryloxide species are of interest as catalysts for asymmetric Diels-Alder reactions (see: Faller, J. W.; D'Alliessi, D. G. Organometallics 2003, 22, 2749. F aller, J. W. ; Lavoie, A. R.; Grimmond, B. J. Organometallics 2002, 21, 1662) and are of potential relevance for nucleophilic phenol functionalization (see: Le Bras, J. ; Amouri, H.; Vaissermann, J. Inorg. Chem. 1998, 37, 5066 and references therein) or carbonylation (see: Dockter, D. W.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1996, 118, 4846. Rees, W. M.; Churchill, M. R.; Fettinger, J. C.; Atwood, J. D. Organometallics 1985, 4, 2179).
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