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While preparing this manuscript we became aware that a group at Universidad Complutense de Madrid had made an analogous compound with N,N′-diphenylformamidinate instead of DAniF ligands. A crystallographic characterization is available. See: M.C. Barral, S. Herrero, R. Jiménez-Aparicio, M.R. Torres, F.A. Urbanos, Inorg. Chem. Commun. 7 (2004); doi: 10.1016/j.inoche. 2003.09.016.
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These two complexes have been isolated from the reaction as crystals and identified by determination of their respective unit cells.
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