Continuous spectroscopic and redox tuning of dinuclear compounds: Chlorotetrakis(μ-N-N′-diarylformamidinato)diruthenium(II, III)

Chemistry Letters

Volumn , Issue 8, 1997, Pages 753-754

  Lin, Chun ^a   Ren, Tong ^a   Valente, Edward J ^b   Zubkowski, Jeffrey D ^c   Smith, Eugene T ^a  

^a Florida Institute of Technology   (United States)

^b MISSISSIPPI COLLEGE   (United States)

^c JACKSON STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001097234     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.753     Document Type: Article

References (20)

1. Part 4. Linear Free Energy Relationships in Dinuclear Compounds, See reference 7 for Parts 1 - 3.
2. F. A. Cotton and R. A. Walton, "Multiple Bonds between Metal Atoms"; Second ed.; Oxford University Press, Oxford (1993).
3. 2, see S. Minakata, E. Imai, Y. Ohshima, K. Inaki, I. Ryu, M. Komatsu, and Y. Ohshiro, Chem. Lett., 1996, 19.
4. 2, see S. Minakata, E. Imai, Y. Ohshima, K. Inaki, I. Ryu, M. Komatsu, and Y. Ohshiro, Chem. Lett., 1996, 19.
5. 2, see S. Minakata, E. Imai, Y. Ohshima, K. Inaki, I. Ryu, M. Komatsu, and Y. Ohshiro, Chem. Lett., 1996, 19.
6. K. M. Kadish, Prog. Inorg. Chem., 34, 435 (1986).
7. S. D. Cummings and R. Eisenberg, J. Am. Chem. Soc. , 118, 1949 (1996).
8. For recent examples, see F. C. Rix, M. Brookhart, and P. S. White, J. Am. Chem. Soc. ,118, 2436 (1996); K. Kato, T. Yamada, T. Takai, S. Inoki, and S. Isayama, Bull. Chem. Soc. Jpn., 63, 179 (1990); E. N. Jacobsen, W. Zhang, and M. L. Guler, J. Am. Chem. Soc., 113, 6703 (1991); S.-B. Park, K. Murata, H. Matsumoto, and H. Nishiyama, Tetrahedron: Asymmetry, 6, 2487 (1995).
9. For recent examples, see F. C. Rix, M. Brookhart, and P. S. White, J. Am. Chem. Soc. ,118, 2436 (1996); K. Kato, T. Yamada, T. Takai, S. Inoki, and S. Isayama, Bull. Chem. Soc. Jpn., 63, 179 (1990); E. N. Jacobsen, W. Zhang, and M. L. Guler, J. Am. Chem. Soc., 113, 6703 (1991); S.-B. Park, K. Murata, H. Matsumoto, and H. Nishiyama, Tetrahedron: Asymmetry, 6, 2487 (1995).
10. For recent examples, see F. C. Rix, M. Brookhart, and P. S. White, J. Am. Chem. Soc. ,118, 2436 (1996); K. Kato, T. Yamada, T. Takai, S. Inoki, and S. Isayama, Bull. Chem. Soc. Jpn., 63, 179 (1990); E. N. Jacobsen, W. Zhang, and M. L. Guler, J. Am. Chem. Soc., 113, 6703 (1991); S.-B. Park, K. Murata, H. Matsumoto, and H. Nishiyama, Tetrahedron: Asymmetry, 6, 2487 (1995).
11. For recent examples, see F. C. Rix, M. Brookhart, and P. S. White, J. Am. Chem. Soc. ,118, 2436 (1996); K. Kato, T. Yamada, T. Takai, S. Inoki, and S. Isayama, Bull. Chem. Soc. Jpn., 63, 179 (1990); E. N. Jacobsen, W. Zhang, and M. L. Guler, J. Am. Chem. Soc., 113, 6703 (1991); S.-B. Park, K. Murata, H. Matsumoto, and H. Nishiyama, Tetrahedron: Asymmetry, 6, 2487 (1995).
12. C. Lin, J. D. Protasiewicz, E. T. Smith, and T. Ren, J. Chem. Soc., Chem. Commun. 1995, 2257 and Inorg. Chem., 35, 6422 (1996); C. Lin, J. D. Protasiewicz, and T. Ren, Inorg. Chem., 35, 7455 (1996).
13. C. Lin, J. D. Protasiewicz, E. T. Smith, and T. Ren, J. Chem. Soc., Chem. Commun. 1995, 2257 and Inorg. Chem., 35, 6422 (1996); C. Lin, J. D. Protasiewicz, and T. Ren, Inorg. Chem., 35, 7455 (1996).
14. C. Lin, J. D. Protasiewicz, E. T. Smith, and T. Ren, J. Chem. Soc., Chem. Commun. 1995, 2257 and Inorg. Chem., 35, 6422 (1996); C. Lin, J. D. Protasiewicz, and T. Ren, Inorg. Chem., 35, 7455 (1996).
15. Results of elemental analysis and crystallographic study (submitted as supplementary materials) are available from TR.
16. F. A. Cotton and T. Ren, Inorg. Chem., 34, 3190 (1995); J. L. Bear, B. Han, S. Huang, and K. M. Kadish, Inorg. Chem., 35, 3012 (1996).
17. F. A. Cotton and T. Ren, Inorg. Chem., 34, 3190 (1995); J. L. Bear, B. Han, S. Huang, and K. M. Kadish, Inorg. Chem., 35, 3012 (1996).
18. V. M. Miskowski and H. B. Gray, Inorg. Chem., 27, 2501 (1988).
19. A plausible explanation is that as the σ(substituent) increases, the E(δ) decreases much faster than the E(π*) due to larger ligand contribution to the former orbital.
20. Numerical simulation was carried out with DigiSim Version 2.1 (BAS, West Lafyette, IN 47906, USA). The simulated CV is submitted as the Supporting Information.