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Volumn 118, Issue 8, 1996, Pages 2008-2012

The diverse reactivity of peroxy ferric porphyrin complexes of electron-rich and electron-poor porphyrins

Author keywords

[No Author keywords available]

Indexed keywords

PORPHYRIN DERIVATIVE;

EID: 0029970639     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953694y     Document Type: Article
Times cited : (82)

References (47)
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    • A nucleophilic peroxo heme species has been proposed for cytochrome P-450 aromatase which converts androgens to estrogens (a) Akhtar, M., Calder, D. L.; Corina, D. L.: Wright. J N. J. Chem. Soc., Chem. Commun. 1981, 129. (b) Cole, P. A.; Robinson, C. H. J. Am. Chem. Soc. 1991, 113, 8130. (c) Graham-Lorence, S.; Amarneh, B.; White, R. E.; Peterson, J. A.: Simpson, E. R. Protein Sci. 1995, 4, 1065.
    • (1981) J. Chem. Soc., Chem. Commun. , pp. 129
    • Akhtar, M.1    Calder, D.L.2    Corina, D.L.3    Wright, J.N.4
  • 13
    • 0000889090 scopus 로고
    • A nucleophilic peroxo heme species has been proposed for cytochrome P-450 aromatase which converts androgens to estrogens (a) Akhtar, M., Calder, D. L.; Corina, D. L.: Wright. J N. J. Chem. Soc., Chem. Commun. 1981, 129. (b) Cole, P. A.; Robinson, C. H. J. Am. Chem. Soc. 1991, 113, 8130. (c) Graham-Lorence, S.; Amarneh, B.; White, R. E.; Peterson, J. A.: Simpson, E. R. Protein Sci. 1995, 4, 1065.
    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 8130
    • Cole, P.A.1    Robinson, C.H.2
  • 14
    • 0029033662 scopus 로고
    • A nucleophilic peroxo heme species has been proposed for cytochrome P-450 aromatase which converts androgens to estrogens (a) Akhtar, M., Calder, D. L.; Corina, D. L.: Wright. J N. J. Chem. Soc., Chem. Commun. 1981, 129. (b) Cole, P. A.; Robinson, C. H. J. Am. Chem. Soc. 1991, 113, 8130. (c) Graham-Lorence, S.; Amarneh, B.; White, R. E.; Peterson, J. A.: Simpson, E. R. Protein Sci. 1995, 4, 1065.
    • (1995) Protein Sci. , vol.4 , pp. 1065
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  • 15
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    • For NO synthase, direct oxidation by the ferric peroxo species has also been proposed. Marietta. M. A. J. Biol. Chem. 1993, 268, 12231.
    • (1993) J. Biol. Chem. , vol.268 , pp. 12231
    • Marietta, M.A.1
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    • Vaz, A.D.N.1    Kessell, K.J.2    Coon, M.J.3
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    • 2 is added to this compound, it is converted to complex 2b. in agreement with the suggestion that the species is the reduced Fe(II) complex. See: (a) Watanabe, Y.; Ishimura, Y. J. Am. Chem. Soc. 1989, 111, 410. (b) Watanabe, Y.; Ishimura, Y. J Am. Chem. Soc. 1989, 111, 8047.
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    • 2 is added to this compound, it is converted to complex 2b. in agreement with the suggestion that the species is the reduced Fe(II) complex. See: (a) Watanabe, Y.; Ishimura, Y. J. Am. Chem. Soc. 1989, 111, 410. (b) Watanabe, Y.; Ishimura, Y. J Am. Chem. Soc. 1989, 111, 8047.
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    • Selke, M.1


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