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Volumn 126, Issue 1, 2004, Pages 56-57

A Dramatic Elongation of the Lifetime of Charge-Separated State by Complexation with Yttrium Triflate in Ferrocene-Anthraquinone Linked Dyad

Author keywords

[No Author keywords available]

Indexed keywords

ANTHRAQUINONE DERIVATIVE; FERROCENE DERIVATIVE; UNCLASSIFIED DRUG; YTTRIUM; YTTRIUM TRIFLATE;

EID: 0346499347     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037025t     Document Type: Article
Times cited : (32)

References (32)
  • 1
    • 0001748542 scopus 로고
    • Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam
    • (a) Wasielewski, M. R. In Photoinduced Electron Transfer; Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam, 1988; Part A. pp 161-206.
    • (1988) Photoinduced Electron Transfer , Issue.PART A , pp. 161-206
    • Wasielewski, M.R.1
  • 11
    • 84955395805 scopus 로고    scopus 로고
    • Chemistry; Balzani, V. Ed.; Wiley-VCH: Weinheim
    • Fukuzumi, S.; Guldi, D. M. In Electron Transfer in Chemistry; Balzani, V. Ed.; Wiley-VCH: Weinheim, 2001; Vol. 2, pp 270-337.
    • (2001) Electron Transfer in Chemistry , vol.2 , pp. 270-337
    • Fukuzumi, S.1    Guldi, D.M.2
  • 18
    • 84955337965 scopus 로고    scopus 로고
    • Balzani, V., Ed.; Wiley-VCH: Weinheim
    • (a) Fukuzumi, S. In Electron Transfer in Chemistry; Balzani, V., Ed.; Wiley-VCH: Weinheim, 2001; Vol. 4. pp 3-67.
    • (2001) Electron Transfer in Chemistry , vol.4 , pp. 3-67
    • Fukuzumi, S.1
  • 23
    • 0032234424 scopus 로고    scopus 로고
    • Electron transfer is also controlled by proton as well as metal ions. For the proton-coupled electron transfer, see: (a) Cukier, R. I.; Nocera, D. G. Annu. Rev. Phys. Chem. 1998, 49, 337.
    • (1998) Annu. Rev. Phys. Chem. , vol.49 , pp. 337
    • Cukier, R.I.1    Nocera, D.G.2
  • 26
    • 85039577866 scopus 로고    scopus 로고
    • note
    • 3 cannot bind with the AQ moiety. For the Lewis acidity of metal triflates, see ref 11.
  • 29
    • 85039580915 scopus 로고    scopus 로고
    • note
    • Since the CS state is observed within 500 fs, the electron transfer may occur from Fc to the singlet excited state of AQ rather than to the triplet excited state which may be formed at the time scale of longer than picoseconds.
  • 31
    • 85039584276 scopus 로고    scopus 로고
    • note
    • 3 (0.42 eV) becomes much smaller than that in its absence (1.28 eV)
  • 32
    • 85039569619 scopus 로고    scopus 로고
    • note
    • 3 has been obtained as large reorganization energy as 2.9 eV, see S9.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.