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Electron transfer is also controlled by proton as well as metal ions. For the proton-coupled electron transfer, see: (a) Cukier, R. I.; Nocera, D. G. Annu. Rev. Phys. Chem. 1998, 49, 337.
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26
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85039577866
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note
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3 cannot bind with the AQ moiety. For the Lewis acidity of metal triflates, see ref 11.
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29
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85039580915
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note
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Since the CS state is observed within 500 fs, the electron transfer may occur from Fc to the singlet excited state of AQ rather than to the triplet excited state which may be formed at the time scale of longer than picoseconds.
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30
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0037134808
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For photoinduced electron transfer from Fc to Q in Fc-Q, see: Fukuzumi, S.; Yoshida, Y.; Okamoto, K.; Imahori, H.; Araki, Y.; Ito, O. J. Am. Chem. Soc. 2002, 124, 6794.
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Fukuzumi, S.1
Yoshida, Y.2
Okamoto, K.3
Imahori, H.4
Araki, Y.5
Ito, O.6
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31
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85039584276
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note
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3 (0.42 eV) becomes much smaller than that in its absence (1.28 eV)
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32
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85039569619
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note
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3 has been obtained as large reorganization energy as 2.9 eV, see S9.
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