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Volumn 125, Issue 49, 2003, Pages 15210-15223

Thermal Activation of Hydrocarbon C-H Bonds Initiated by a Tungsten Allyl Complex

Author keywords

[No Author keywords available]

Indexed keywords

THERMOLYSIS;

EID: 0344236071     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037076q     Document Type: Article
Times cited : (45)

References (69)
  • 2
    • 0037198618 scopus 로고    scopus 로고
    • and references therein
    • Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507 and references therein.
    • (2002) Nature , vol.417 , pp. 507
    • Labinger, J.A.1    Bercaw, J.E.2
  • 10
    • 0345471141 scopus 로고    scopus 로고
    • note
    • Direct evidence for endo- versus exo-allyl conformations using selective NOE NMR spectroscopy is sometimes not available, and logical inferences must be made to ascertain the solution structure. For example, irradiation of the signal due to the central allyl H atom leading to an NOE enhancement of the Cp* methyl H atoms signal is direct evidence for an exo configuration. However, its absence, and hence the implication of an endo configuration, must be confirmed by irradiation of the trans Me group signal that should exhibit an NOE enhancement of the Cp* ring signal.
  • 14
    • 0344177298 scopus 로고    scopus 로고
    • note
    • A single-crystal X-ray crystallographic analysis of 6 has been performed. Its solid-state structural features are similiar to those exhibited by other p-xylene aryl C-H-activated tungsten nitrosyl complexes.
  • 44
    • 0345471137 scopus 로고    scopus 로고
    • note
    • Preliminary single-crystal X-ray crystallographic analysis of 22 has confirmed the atomic connectivity shown in eq 8. However, the quality of the diffraction data collected precludes meaningful discussion of its metrical parameters.
  • 54
    • 0345471136 scopus 로고    scopus 로고
    • note
    • 3.
  • 67
    • 0142082553 scopus 로고    scopus 로고
    • Molecular Structure Corp.: The Woodlands, TX
    • CrystalClear: Version 1.3.5b20; Molecular Structure Corp.: The Woodlands, TX, 2002.
    • (2002) CrystalClear: Version 1.3.5b20
  • 68
    • 0344177294 scopus 로고    scopus 로고
    • teXsan; Molecular Structure Corp.: The Woodlands, TX, 1985 and 1992
    • teXsan; Molecular Structure Corp.: The Woodlands, TX, 1985 and 1992.
  • 69
    • 0004150157 scopus 로고    scopus 로고
    • Sheldrick, G. M. University of Göttingen: Germany
    • SHELXL97; Sheldrick, G. M. University of Göttingen: Germany, 1997.
    • (1997) SHELXL97


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.