Rhodium(I) complexes with π-coordinated arylallene. Structures in the solid state and in solution and reaction with arylallene to give rhodacyclopentane

Organometallics

Volumn 17, Issue 10, 1998, Pages 2037-2045

  Choi, Jun Chul ^a   Sarai, Susumu ^a   Koizumi, Take Aki ^a   Osakada, Kohtaro ^a   Yamamoto, Takakazu ^a  

^a Tokyo Institute of Technology ^*  (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000761499     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970931s     Document Type: Article

References (49)

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38. 1H NMR signal at δ 8.58 corresponds to two hydrogens of 1a in the solution. Rotation of the C-C single bond between allenyl and phenyl groups seems to occur much faster than the NMR time scale.
39. 1J(CH) value is obtained as average of that of the two ortho C-H groups of the ligand. The coupling constants of the C-H groups with and without the agostic interaction are estimated as 154 and 160 Hz, respectively.
40. 31P NMR peak positions of 1a and of 4a′ is not feasible.
41. 3 dissociation from 2a in the previous report are also unreliable.
42. 3 complexes in the present study.
43. 3 complexes in the present study.
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