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Volumn 17, Issue 10, 1998, Pages 2037-2045

Rhodium(I) complexes with π-coordinated arylallene. Structures in the solid state and in solution and reaction with arylallene to give rhodacyclopentane

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0000761499     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970931s     Document Type: Article
Times cited : (22)

References (49)
  • 38
    • 85034276843 scopus 로고    scopus 로고
    • note
    • 1H NMR signal at δ 8.58 corresponds to two hydrogens of 1a in the solution. Rotation of the C-C single bond between allenyl and phenyl groups seems to occur much faster than the NMR time scale.
  • 39
    • 85034293358 scopus 로고    scopus 로고
    • note
    • 1J(CH) value is obtained as average of that of the two ortho C-H groups of the ligand. The coupling constants of the C-H groups with and without the agostic interaction are estimated as 154 and 160 Hz, respectively.
  • 40
    • 85034287443 scopus 로고    scopus 로고
    • note
    • 31P NMR peak positions of 1a and of 4a′ is not feasible.
  • 41
    • 85034280885 scopus 로고    scopus 로고
    • note
    • 3 dissociation from 2a in the previous report are also unreliable.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.