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Volumn 18, Issue 8, 1999, Pages 1389-1401

Fluxional η3-allyl derivatives of ansa-scandocenes and an ansa-yttrocene. Measurements of the barriers for the η3 to η1 process as an indicator of olefin binding energy to d0 metallocenes

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0000749724     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980893s     Document Type: Article
Times cited : (58)

References (69)
  • 5
    • 33646918898 scopus 로고
    • Ph.D. Thesis, California Institute of Technology
    • (d) Doherty, N. M. Ph.D. Thesis, California Institute of Technology, 1984.
    • (1984)
    • Doherty, N.M.1
  • 13
  • 52
    • 85085632641 scopus 로고    scopus 로고
    • 3 coordinated, although likely, has not been unambiguously established
    • 3 coordinated, although likely, has not been unambiguously established.
  • 54
    • 33646922604 scopus 로고    scopus 로고
    • Stryker has argued that coordination of carbon monoxide to a d° metallocene allyl complex induces strong σ → π* donation from the neighboring allyl ligand, inhibiting fluxionality in the allyl fragment
    • Stryker has argued that coordination of carbon monoxide to a d° metallocene allyl complex induces strong σ → π* donation from the neighboring allyl ligand, inhibiting fluxionality in the allyl fragment.
  • 55
    • 33646919802 scopus 로고    scopus 로고
    • See, for example; (a) Reference 4a
    • See, for example; (a) Reference 4a.
  • 64
    • 33646901601 scopus 로고    scopus 로고
    • The fits are most sensitive to the trial rate constants in these temperature regions
    • The fits are most sensitive to the trial rate constants in these temperature regions.
  • 65
    • 85085633668 scopus 로고    scopus 로고
    • 1
    • 1.
  • 66
    • 33646949997 scopus 로고    scopus 로고
    • Since the two sides of the metallocene wedge are the same for the racemic isomers, the statistical factor here is the same as for the more symmetric 1
    • Since the two sides of the metallocene wedge are the same for the racemic isomers, the statistical factor here is the same as for the more symmetric 1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.