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Charge assisted hydrogen bonding between aqua-metal ions and sulfonate anions has been studied as a means to construct infinite frameworks, see a) S. A. Dalrymple, M. Parvez, G. K. H. Shimizu, Inorg. Chem. 2002, 41, 6986;
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The supramolecular chemistry of sulfonated calixarenes with hydrated lanthanide and other cations have been explored by Atwood and Raston. These inclusion compounds can form extended structures in the solid-state. See: a) J. L. Atwood, L. J. Barbour, S. J. Dagarno, C. L Raston, H. R. Webb, J. Chem. Soc. Dalton Trans. 2002, 4351;
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60
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0345242192
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-
note
-
Compound 4 and preliminary gas uptake results has been the subject of an earlier communication. See ref. [10].
-
-
-
-
61
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0003062688
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4,5-Dihydroxybenzene-1,3-disulfonate is used as a complexometric indicator (commercially known as Tiron) for divalent transition metal ions via 4,5-diol chelation, see: a) S. Abe, T. Saito, M. Suda, Anal. Chim. Acta 1986, 181, 203;
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68
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-
0344379383
-
-
note
-
A detailed view of the hydrogen bonding in this compound is provided in the supplemental material. For a discussion on hydrogen bonding patterns between organosulfonates hexaaquo metal cations see refs. [8a] and [8b].
-
-
-
-
69
-
-
24544456394
-
-
unpublished results
-
The anchoring role of the catechol moiety is an important feature in this network. As a comparison, Ba(1,3-benzenedisulfonate) forms a dense 2D layered structure: A. P. Côté, G. K. H. Shimizu, unpublished results.
-
-
-
Côté, A.P.1
Shimizu, G.K.H.2
-
70
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0345242182
-
-
note
-
2O, was difficult owing to effects of our thermogravimetric apparatus that seems to also have an affinity for this gas. This made reliable measurement of mass changes not possible.
-
-
-
-
71
-
-
0344811084
-
-
note
-
2S.
-
-
-
-
72
-
-
0344811083
-
-
note
-
2 due to the presence of a large excess of cations driving complex ion formation.
-
-
-
-
73
-
-
0345242187
-
-
note
-
-1 = 0.351 mmol, after washing and drying. Therefore, the number of measured equivalents sorbed = 0.351 mmol/0.566 mmol = 0.62. A photograph showing the formation of PbS in this experiment is provided as supplemental material.
-
-
-
-
75
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0345673920
-
-
note
-
-1. Please see Supporting Information for structural illustrations, further experimental information, and connectivity data.
-
-
-
-
76
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0345673921
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