A springlike 3D-coordination network that shrinks or swells in a crystal-to-crystal manner upon guest removal or readsorption

Angewandte Chemie - International Edition

Volumn 41, Issue 18, 2002, Pages 3392-3395

  Biradha, Kumar ^a   Fujita, Makoto ^a,b  

^a JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

Host guest systems; Solid state structures; X ray diffraction; Zeolite analogues; Zinc

Indexed keywords

ADSORPTION; MOLECULES; ZINC;

LIGANDS;

CRYSTALS;

ZINC;

ADSORPTION; ARTICLE; CATALYSIS; COMPLEX FORMATION; CRYSTAL; CRYSTAL STRUCTURE; POROSITY;

EID: 0037119726     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO;2-V     Document Type: Article

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33. Examples of dynamic coordination networks: a) R. Kitaura, K. Fujimoto, S.-i. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 149; Angew. Chem. Int. Ed. 2002, 41, 141; L. C. Tabares, J. A. R. Navarro, J. M. Salas, J. Am. Chem. Soc. 2001,123,383; D. V. Soldatov, J. A. Ripmeester, S. I. Shergina, I. E. Sokolov, A. S. Zanina, S. A. Gromilov, Y. A. Dyadin, J. Am. Chem. Soc. 1999, 121, 4179; G. Alberti, S. Murcia-Mascarós, R. Vivani, J. Am. Chem. Soc. 1998, 120, 9291; K. S. Min, M. P. Suh, J. Am. Chem. Soc. 2000, 122, 6384.
34. Examples of dynamic coordination networks: a) R. Kitaura, K. Fujimoto, S.-i. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 149; Angew. Chem. Int. Ed. 2002, 41, 141; L. C. Tabares, J. A. R. Navarro, J. M. Salas, J. Am. Chem. Soc. 2001,123,383; D. V. Soldatov, J. A. Ripmeester, S. I. Shergina, I. E. Sokolov, A. S. Zanina, S. A. Gromilov, Y. A. Dyadin, J. Am. Chem. Soc. 1999, 121, 4179; G. Alberti, S. Murcia-Mascarós, R. Vivani, J. Am. Chem. Soc. 1998, 120, 9291; K. S. Min, M. P. Suh, J. Am. Chem. Soc. 2000, 122, 6384.
35. Examples of dynamic coordination networks: a) R. Kitaura, K. Fujimoto, S.-i. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 149; Angew. Chem. Int. Ed. 2002, 41, 141; L. C. Tabares, J. A. R. Navarro, J. M. Salas, J. Am. Chem. Soc. 2001,123,383; D. V. Soldatov, J. A. Ripmeester, S. I. Shergina, I. E. Sokolov, A. S. Zanina, S. A. Gromilov, Y. A. Dyadin, J. Am. Chem. Soc. 1999, 121, 4179; G. Alberti, S. Murcia-Mascarós, R. Vivani, J. Am. Chem. Soc. 1998, 120, 9291; K. S. Min, M. P. Suh, J. Am. Chem. Soc. 2000, 122, 6384.
36. Examples of dynamic coordination networks: a) R. Kitaura, K. Fujimoto, S.-i. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 149; Angew. Chem. Int. Ed. 2002, 41, 141; L. C. Tabares, J. A. R. Navarro, J. M. Salas, J. Am. Chem. Soc. 2001,123,383; D. V. Soldatov, J. A. Ripmeester, S. I. Shergina, I. E. Sokolov, A. S. Zanina, S. A. Gromilov, Y. A. Dyadin, J. Am. Chem. Soc. 1999, 121, 4179; G. Alberti, S. Murcia-Mascarós, R. Vivani, J. Am. Chem. Soc. 1998, 120, 9291; K. S. Min, M. P. Suh, J. Am. Chem. Soc. 2000, 122, 6384.
37. Examples of dynamic coordination networks: a) R. Kitaura, K. Fujimoto, S.-i. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 149; Angew. Chem. Int. Ed. 2002, 41, 141; L. C. Tabares, J. A. R. Navarro, J. M. Salas, J. Am. Chem. Soc. 2001,123,383; D. V. Soldatov, J. A. Ripmeester, S. I. Shergina, I. E. Sokolov, A. S. Zanina, S. A. Gromilov, Y. A. Dyadin, J. Am. Chem. Soc. 1999, 121, 4179; G. Alberti, S. Murcia-Mascarós, R. Vivani, J. Am. Chem. Soc. 1998, 120, 9291; K. S. Min, M. P. Suh, J. Am. Chem. Soc. 2000, 122, 6384.
38. S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558; Angew. Chem. Int. Ed. 1998, 37, 1460.
39. S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558; Angew. Chem. Int. Ed. 1998, 37, 1460.
40. Some interpenetrated networks with a (10,3)-b configuration: a) G. B. Gardner, Y.-H. Kiang, S. Lee, A. Asgaonkar, D. Venkatraman, J. Am. Chem. Soc. 1996, 118, 6947: b) L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 4562; c) F. A. Cotton, C. Lin, C. A. Murillo, J. Chem. Soc. Dalton Trans. 2001, 499; d) O. M. Yaghi, H. Li, J. Am. Chem. Soc. 1995, 117, 10401.
41. Some interpenetrated networks with a (10,3)-b configuration: a) G. B. Gardner, Y.-H. Kiang, S. Lee, A. Asgaonkar, D. Venkatraman, J. Am. Chem. Soc. 1996, 118, 6947: b) L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 4562; c) F. A. Cotton, C. Lin, C. A. Murillo, J. Chem. Soc. Dalton Trans. 2001, 499; d) O. M. Yaghi, H. Li, J. Am. Chem. Soc. 1995, 117, 10401.
42. Some interpenetrated networks with a (10,3)-b configuration: a) G. B. Gardner, Y.-H. Kiang, S. Lee, A. Asgaonkar, D. Venkatraman, J. Am. Chem. Soc. 1996, 118, 6947: b) L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 4562; c) F. A. Cotton, C. Lin, C. A. Murillo, J. Chem. Soc. Dalton Trans. 2001, 499; d) O. M. Yaghi, H. Li, J. Am. Chem. Soc. 1995, 117, 10401.
43. Some interpenetrated networks with a (10,3)-b configuration: a) G. B. Gardner, Y.-H. Kiang, S. Lee, A. Asgaonkar, D. Venkatraman, J. Am. Chem. Soc. 1996, 118, 6947: b) L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 4562; c) F. A. Cotton, C. Lin, C. A. Murillo, J. Chem. Soc. Dalton Trans. 2001, 499; d) O. M. Yaghi, H. Li, J. Am. Chem. Soc. 1995, 117, 10401.
44. 2 = 0.2316.
45. 2 = 0.1922.
46. 2 = 0.2720.
47. 2 = 0.1462.
48. 2 = 0.2486.
49. Unit cell parameters for 2 after complete guest removal by heating on hotplate for 10 mins at 170°C, the crystals broke into small pieces and became less transparent. The complete guest removal was confirmed by GC analysis: a = 14.573(19), b = 17.268(23), c = 28.044(38) Å, α = 89.685(15)°; β = 76.956(14)°; γ = 73.794(12)°. Heating the crystals of 3 to 170°C resulted in similar cell parameters to those described above.
50. The powder diffraction patterns for 2 monitored at various time intervals are in the Supporting Information.
51. 2 = 0.1589.
52. 1 = 0.0456, wR2 = 0.1038.