A Ruthenium Nitrosyl that Rapidly Delivers NO to Proteins in Aqueous Solution upon Short Exposure to UV Light

Inorganic Chemistry

Volumn 42, Issue 23, 2003, Pages 7363-7365

  Patra, Apurba K ^a   Mascharak, Pradip K ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; CHLORINE DERIVATIVE; CYTOCHROME C OXIDASE; MYOGLOBIN; NITRIC OXIDE; PROTEIN; RUTHENIUM DERIVATIVE; RUTHENIUM NITROSYL DERIVATIVE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; COMPLEX FORMATION; LIGHT EXPOSURE; PROTON NUCLEAR MAGNETIC RESONANCE; SPECTROSCOPY; SYNTHESIS; ULTRAVIOLET RADIATION; X RAY DIFFRACTION;

ANIMALS; HORSES; MOLECULAR STRUCTURE; MYOCARDIUM; MYOGLOBIN; NITRIC OXIDE; ORGANOMETALLIC COMPOUNDS; RUTHENIUM; ULTRAVIOLET RAYS; WATER; X-RAY DIFFRACTION;

EID: 0242609802     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic030110h     Document Type: Article

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27. max = 384 nm) and related complexes. Complex 1 exhibits this band at 500 nm. Collectively, the photolability of NO noted with 1 and 3 under lights of different energy (vis and UV, respectively) indicates that NO labilization may result from population of a dissociative excited state as suggested by Ford and co-workers.