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Volumn 20, Issue 16, 2001, Pages 3370-3372

X-ray structure and reactivity of (η4-tetraphenylcyclopentadienone)(CO)2 Ru(HOCHMe2): Unexpected stability of the neutral 2-propanol-ruthenium(0) complex with respect to β-hydride elimination

Author keywords

[No Author keywords available]

Indexed keywords

ACIDIFICATION; PROPANOL RUTHENIUM COMPLEX; TETRAPHENYLCYCLOPENTADIENONE; X RAY STRUCTURE;

EID: 0035817667     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0103198     Document Type: Article
Times cited : (20)

References (31)
  • 19
    • 0011442342 scopus 로고    scopus 로고
    • note
    • w = 0.0837, GOF = 1.123. (8) Two sites are possible for the location of the hydroxyl proton in the crystal structure. The distance to the carbonyl oxygen is 2.190 Å for an intramolecular hydrogen bonding interaction, while that for an intermolecular one is 1.843 Å.
  • 20
    • 0011446124 scopus 로고    scopus 로고
    • note
    • W = 0.0837, GOF = 1.123.
  • 21
    • 0011452354 scopus 로고    scopus 로고
    • note
    • Two sites are possible for the location of the hydroxyl proton in the crystal structure. The distance to the carbonyl oxygen is 2.190 Å for an intramolecular hydrogen bonding interaction, while that for an intermolecular one is 1.843 Å.
  • 22
    • 0001849590 scopus 로고
    • note
    • 5-coordination character. The hydrogen bonding interaction would be responsible for this character. Blum, Y.; Shvo, Y.; Chodosh, D. F. Inorg. Chim. Acta 1985, 97, L25.
    • (1985) Inorg. Chim. Acta , vol.97
    • Blum, Y.1    Shvo, Y.2    Chodosh, D.F.3
  • 29
    • 0011394556 scopus 로고    scopus 로고
    • note
    • 4Ru: C, 71.74; H, 3.61. Found: C, 71.51; H, 3.93.
  • 30
    • 0011442343 scopus 로고    scopus 로고
    • note
    • 2: C, 72.88; H, 3.92. Found: C, 73.04; H, 4.15.
  • 31
    • 0011446126 scopus 로고    scopus 로고
    • note
    • 2: C, 66.18; H, 3.85. Found: C, 65.90; H, 3.61.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.