RuHCl(diphosphine)(diamine): Catalyst precursors for the stereoselective hydrogenation of ketones and imines

Organometallics

Volumn 20, Issue 6, 2001, Pages 1047-1049

  Abdur Rashid, Kamaluddin ^a   Lough, Alan J ^a   Morris, Robert H ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALKOXIDE BASE; DIPHOSPHINE DIAMINE; STEREOSELECTIVE HYDROGENATION;

AMINES; CATALYSIS; COMPLEXATION; HYDROGENATION; KETONES; RUTHENIUM COMPOUNDS; STEREOCHEMISTRY; SUBSTITUTION REACTIONS;

ORGANOMETALLICS;

EID: 0035911986     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om001054k     Document Type: Article

References (21)

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9. 1H} NMR: 34.4 ppm (s).
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19. -1 (NH). Anal. Calcd: C, 65.34; H, 5.48; N, 3.17. Found: C, 65.69; H, 5.71; N, 3.19.
20. -1 (NH).
21. iPr. Evaporation of the hexanes under reduced pressure resulted in pure phenyl(1-phenyl-ethyl)amine. Yield: 1.98 g, 98%.