Ten-Electron Coordination and Reactivity of an Arylphosphinidene Ligand

Journal of the American Chemical Society

Volumn 125, Issue 43, 2003, Pages 13044-13045

  García, M Esther ^a   Riera, Víctor ^a   Ruiz, Miguel A ^a   Sáez, David ^a   Hamidov, Hayrullo ^b   Jeffery, John C ^b   Riis Johannessent, Thomas ^b  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; MOLYBDENUM; PHOSPHINE DERIVATIVE;

ARTICLE; CALCULATION; COMPLEX FORMATION; DESULFURIZATION; ELECTRON TRANSPORT; REACTION ANALYSIS; ULTRAVIOLET RADIATION;

EID: 0142184908     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037293r     Document Type: Article

References (24)

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8. 2)].
9. 3, T = 100 K, Z = 4, R = 1.94, GOF = 1.052.
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13. The structures were optimized using unrestricted B3LYP theory, together with standard 6-3 IG* on all atoms except Mo, for which the Jaguar tfiple-ζ form of the standard Los Alamos ECP basis set (LACV3P) was used. Calculations were performed with the Jaguar 4.1 program package (Schrödinger, Inc., Portland, OR, 1995-2002).
14. 2)].
15. 1H} NMR (162.09 MHz, 213 K) δ 644.6 (s, μ-PR*).
16. 3)].
17. 3, T = 100 K, Z = 4, R = 3.29, GOF = 0.910.
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