High yield synthesis and reactivity of a phosphinidene bridged dimolybdenum complex

Journal of the American Chemical Society

Volumn 124, Issue 48, 2002, Pages 14304-14305

  Esther Garcia M ^a   Riera, Víctor ^a   Ruiz, Miguel A ^a   Sáez, David ^a   Vaissermann, Jacqueline ^b   Jeffery, John C ^c  

^a UNIVERSITY OF OVIEDO   (Spain)

^b SORBONNE UNIVERSITÉ   (France)

^c UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

MOLYBDENUM COMPLEX; PHOSPHINE DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CRYSTAL STRUCTURE; LIGAND BINDING; MOLECULAR STABILITY; OXIDATION; PHOTOLYSIS; PROTON TRANSPORT; REACTION ANALYSIS; SYNTHESIS;

EID: 0037021512     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja021072o     Document Type: Article

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15. 2, 243 K): δ 80.5 (s, μ-PHR*).
16. 2): δ 724.9 (s, μ-PR*).
17. 2): δ 596.4 (s, μ-PR*).
18. 3 T = 295 K, Z = 4, R = 0.042, GOF = 1.13.
19. 1H} NMR (121.51 MHz): δ 166.8 (s, μ-P).
20. 3, T = 295 K, Z = 4, R = 0.0599, GOF = 0.99.
21. Cowley, A. H.; Barron, A. R. Acc. Chem. Res. 1988, 21, 81.
22. Hey-Hawkins, E.; Kurz, S. J. Organomet. Chem. 1994, 479, 125.
23. CP = 14, μ-CO), 98.0 (s, Cp)
24. CP = 64, HCP)
25. 3, T = 173(2) K, Z = 4, R = 0.0368, GOF = 0.955.