Hydrogenases in the "active" state: Determination of g-matrix axes and electron spin distribution at the active site by 1H ENDOR spectroscopy

Journal of Biological Inorganic Chemistry

Volumn 7, Issue 1-2, 2002, Pages 177-194

  Müller, Arnd ^a   Tscherny, Irene ^a   Kappl, Reinhard ^c   Hatchikian, E Claude ^b   Hüttermann, Jürgen ^c   Cammack, Richard ^a  

^a KING'S COLLEGE LONDON   (United Kingdom)

^b CNRS   (France)

^c SAARLAND UNIVERSITY   (Germany)

Author keywords

Dinuclear centre; Electron nuclear double resonance spectroscopy; Electron paramagnetic resonance spectroscopy; Hydrogenases; Nickel

Indexed keywords

BETA METHYLENE; CARBENE; CYSTEINE; HYDROGENASE; IRON; NICKEL; POLYMACON; PROTON; SELENIUM; SULFUR; UNCLASSIFIED DRUG; DEUTERIUM; NICKEL IRON HYDROGENASE; NICKEL IRON SELENIUM HYDROGENASE; NICKEL-IRON HYDROGENASE; NICKEL-IRON-SELENIUM HYDROGENASE;

AMINO ACID SUBSTITUTION; ANISOTROPY; ARTICLE; CRYSTALLOGRAPHY; DESULFOMICROBIUM; DESULFOMICROBIUM BACULATUM; DESULFOVIBRIO GIGAS; DEUTERIUM HYDROGEN EXCHANGE; ELECTRON NUCLEAR DOUBLE RESONANCE; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; ENZYME MECHANISM; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; SIMULATION; SPATIAL ORIENTATION; BINDING SITE; CHEMICAL STRUCTURE; CHEMISTRY; COMPUTER SIMULATION; ELECTRON; ENZYMOLOGY; METABOLISM; PROTEOBACTERIA; SPECTROSCOPY;

DESULFOMICROBIUM; DESULFOMICROBIUM BACULATUM; DESULFOVIBRIO GIGAS;

BINDING SITES; COMPUTER SIMULATION; CYSTEINE; DEUTERIUM; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; HYDROGENASE; IRON; MODELS, MOLECULAR; NICKEL; PROTEOBACTERIA; PROTONS; SELENIUM; SPECTRUM ANALYSIS; SULFUR;

EID: 0036358619     PISSN: 09498257     EISSN: None     Source Type: Journal    
DOI: 10.1007/s007750100285     Document Type: Article

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