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Volumn 1, Issue 19, 2003, Pages 3418-3429

Model dialkyl peroxides of the fenton mechanistic probe 2-methyl-1-phenyl-2-propyl hydroperoxide (MPPH): Kinetic probes for dissociative electron transfer

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; CHEMICAL BONDS; DISSOCIATION; ELECTROCHEMISTRY; PEROXIDES; REDUCTION;

EID: 0142094523     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b305348b     Document Type: Article
Times cited : (18)

References (107)
  • 56
    • 0004164999 scopus 로고
    • John Wiley& Sons Ltd, New York
    • Organic Peroxides, ed. W. Ando, John Wiley& Sons Ltd, New York, 1992.
    • (1992) Organic Peroxides
    • Ando, W.1
  • 58
    • 0001887557 scopus 로고
    • ed. P. S. Mariano, JAI Press Inc., Greenwich, CT
    • J.-M. Savéant, in Advances in Electron Transfer Chemistry, ed. P. S. Mariano, JAI Press Inc., Greenwich, CT, 1994, vol. 4, pp. 53-116.
    • (1994) Advances in Electron Transfer Chemistry , vol.4 , pp. 53-116
    • Savéant, J.-M.1
  • 62
    • 0142061695 scopus 로고    scopus 로고
    • note
    • The Butler-Volmer model of electrode kinetics implies the transfer coefficient is a constant over a potential range, which is contrary to the observed experimental results. See reference 56.
  • 66
    • 0142029427 scopus 로고    scopus 로고
    • note
    • 1/2 C* where n is the overall electron consumption, A is the electrode area, D is the diffusion coefficient, and C* is the substrate concentration
  • 67
    • 0142093006 scopus 로고    scopus 로고
    • note
    • lim-I(t)/i(t));
  • 68
    • 0142124706 scopus 로고    scopus 로고
    • note
    • 1/δE.
  • 71
    • 0142029681 scopus 로고    scopus 로고
    • note
    • No trans-stilbene was observed as reported in the indirect reduction of some benzyl halides. See reference 63. Incidentally, dihydro-anthracene and stilbene have the identical exact mass and similar GC retention times.
  • 73
    • 0003570790 scopus 로고    scopus 로고
    • ed. H. Fischer, Landolt-Börnstein Group II, Springer-Verlag, Berlin
    • J. A. Howard and J. Lusztyk, Radical Reaction Rates in Liquids, ed. H. Fischer, Landolt-Börnstein Group II, Springer-Verlag, Berlin, vol. 18, subvol. D1, 1997.
    • (1997) Radical Reaction Rates in Liquids , vol.18 D1
    • Howard, J.A.1    Lusztyk, J.2
  • 95
    • 0142093004 scopus 로고    scopus 로고
    • note
    • -1.
  • 96
    • 0142124705 scopus 로고    scopus 로고
    • note
    • RO./RO- was used.
  • 97
    • 0142029426 scopus 로고    scopus 로고
    • note
    • NIST Standard Reference Database; NIST Standard Reference Database and Properties Database and Estimation Program, U. S. Department of Commerce, Gaithersburg, MD, 2003.
  • 100
    • 0142093005 scopus 로고    scopus 로고
    • note
    • AB are the radius of the donor and acceptor, and μ is the reduced mass. See reference 93.
  • 102
    • 0142061459 scopus 로고    scopus 로고
    • note
    • 1/2 where M is the molar mass.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.