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Volumn 121, Issue 26, 1999, Pages 6330-6331

Evidence for a nonheme Fe(IV)=O species in the intramolecular hydroxylation of a phenyl moiety [13]

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; ALKENE; CYTOCHROME P450; IRON; ISOPENICILLIN N SYNTHETASE; OXYGEN; OXYGENASE;

EID: 0033532840     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja990233u     Document Type: Letter
Times cited : (88)

References (34)
  • 17
    • 0345313275 scopus 로고    scopus 로고
    • Abbreviations: TPA, tris(2-pyridylmethyl)amine; 6-Ph-TPA, bis(2-pyridylmethyl)-6-phenyl-2-pyridylmethylamine; 6-Me-TPA, bis(2-pyridylmethyl)-6-methyl-2-pyridylmethylamine; MPPH, 2-methyl-1-phenyl-2-propyl hydroperoxide; DMF, N,N-dimethylformamide
    • Abbreviations: TPA, tris(2-pyridylmethyl)amine; 6-Ph-TPA, bis(2-pyridylmethyl)-6-phenyl-2-pyridylmethylamine; 6-Me-TPA, bis(2-pyridylmethyl)-6-methyl-2-pyridylmethylamine; MPPH, 2-methyl-1-phenyl-2-propyl hydroperoxide; DMF, N,N-dimethylformamide.
  • 20
    • 0344450382 scopus 로고    scopus 로고
    • 2) = 1.080
    • 2) = 1.080.
  • 21
    • 0344882210 scopus 로고    scopus 로고
    • The molecular modeling program Chem3D was used to manipulate the atomic coordinates obtained from the X-ray structure of 1
    • The molecular modeling program Chem3D was used to manipulate the atomic coordinates obtained from the X-ray structure of 1.
  • 23
    • 0345313274 scopus 로고    scopus 로고
    • 1BuOOH is needed to achieve the highest yield of 2
    • 1BuOOH is needed to achieve the highest yield of 2.
  • 24
    • 0345313272 scopus 로고    scopus 로고
    • 2) = 1.015
    • 2) = 1.015.
  • 25
    • 0344019076 scopus 로고    scopus 로고
    • -1) = 469, 502*, 644, 683*, 841, 873 (* = low-spin component)
    • -1) = 469, 502*, 644, 683*, 841, 873 (* = low-spin component).
  • 28
    • 0344019077 scopus 로고    scopus 로고
    • The product solution was analyzed by gas chromatography following removal of the iron(III) complexes by passage through a silica gel column
    • The product solution was analyzed by gas chromatography following removal of the iron(III) complexes by passage through a silica gel column.
  • 30
    • 0344019075 scopus 로고    scopus 로고
    • 16O derivative is observed
    • 16O derivative is observed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.