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Volumn 5, Issue 9, 2003, Pages 1479-1482

Synthesis, characterization, and catalytic activity of N-heterocyclic carbene (NHC) palladacycle complexes

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUP; AMINE; AROMATIC AMINE; CARBENOID; DIMER; HALIDE; HETEROCYCLIC COMPOUND; KETONE; LIGAND; MONOMER; PALLADIUM; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE;

EID: 0141742292     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol034264c     Document Type: Article
Times cited : (297)

References (36)
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    • For reviews see: (a) Jafarpour, L.; Grasa, G. A.; Viciu, M. S.; Hillier, A. C.; Nolan, S. P. Chim. Oggi 2001, 7/8, 10-16. (b) Jafarpour, L.; Nolan S. P. Adv. Organomet. Chem. 2000, 46, 181-222. (c) Weskamp, T.; Bohm, V. P. W.; Herrmann, W. A. J. Organomet. Chem., 2000, 1-2, 12-22. (d) Rigby, J. H.; Cavezza, A.; Ahmed, G. J. Am. Chem. Soc. I996, 118, 12848-12849. (e) Herrmann, W. A. Angew. Chem., Int. Ed. 2002, 8, 1290-1309.
    • (2001) Chim. Oggi , vol.7-8 , pp. 10-16
    • Jafarpour, L.1    Grasa, G.A.2    Viciu, M.S.3    Hillier, A.C.4    Nolan, S.P.5
  • 9
    • 35448936556 scopus 로고    scopus 로고
    • For reviews see: (a) Jafarpour, L.; Grasa, G. A.; Viciu, M. S.; Hillier, A. C.; Nolan, S. P. Chim. Oggi 2001, 7/8, 10-16. (b) Jafarpour, L.; Nolan S. P. Adv. Organomet. Chem. 2000, 46, 181-222. (c) Weskamp, T.; Bohm, V. P. W.; Herrmann, W. A. J. Organomet. Chem., 2000, 1-2, 12-22. (d) Rigby, J. H.; Cavezza, A.; Ahmed, G. J. Am. Chem. Soc. I996, 118, 12848-12849. (e) Herrmann, W. A. Angew. Chem., Int. Ed. 2002, 8, 1290-1309.
    • (2000) Adv. Organomet. Chem. , vol.46 , pp. 181-222
    • Jafarpour, L.1    Nolan, S.P.2
  • 10
    • 0002893108 scopus 로고    scopus 로고
    • For reviews see: (a) Jafarpour, L.; Grasa, G. A.; Viciu, M. S.; Hillier, A. C.; Nolan, S. P. Chim. Oggi 2001, 7/8, 10-16. (b) Jafarpour, L.; Nolan S. P. Adv. Organomet. Chem. 2000, 46, 181-222. (c) Weskamp, T.; Bohm, V. P. W.; Herrmann, W. A. J. Organomet. Chem., 2000, 1-2, 12-22. (d) Rigby, J. H.; Cavezza, A.; Ahmed, G. J. Am. Chem. Soc. I996, 118, 12848-12849. (e) Herrmann, W. A. Angew. Chem., Int. Ed. 2002, 8, 1290-1309.
    • (2000) J. Organomet. Chem. , vol.1-2 , pp. 12-22
    • Weskamp, T.1    Bohm, V.P.W.2    Herrmann, W.A.3
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    • 0030482159 scopus 로고    scopus 로고
    • For reviews see: (a) Jafarpour, L.; Grasa, G. A.; Viciu, M. S.; Hillier, A. C.; Nolan, S. P. Chim. Oggi 2001, 7/8, 10-16. (b) Jafarpour, L.; Nolan S. P. Adv. Organomet. Chem. 2000, 46, 181-222. (c) Weskamp, T.; Bohm, V. P. W.; Herrmann, W. A. J. Organomet. Chem., 2000, 1-2, 12-22. (d) Rigby, J. H.; Cavezza, A.; Ahmed, G. J. Am. Chem. Soc. I996, 118, 12848-12849. (e) Herrmann, W. A. Angew. Chem., Int. Ed. 2002, 8, 1290-1309.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 12848-12849
    • Rigby, J.H.1    Cavezza, A.2    Ahmed, G.3
  • 12
    • 0037090932 scopus 로고    scopus 로고
    • For reviews see: (a) Jafarpour, L.; Grasa, G. A.; Viciu, M. S.; Hillier, A. C.; Nolan, S. P. Chim. Oggi 2001, 7/8, 10-16. (b) Jafarpour, L.; Nolan S. P. Adv. Organomet. Chem. 2000, 46, 181-222. (c) Weskamp, T.; Bohm, V. P. W.; Herrmann, W. A. J. Organomet. Chem., 2000, 1-2, 12-22. (d) Rigby, J. H.; Cavezza, A.; Ahmed, G. J. Am. Chem. Soc. I996, 118, 12848-12849. (e) Herrmann, W. A. Angew. Chem., Int. Ed. 2002, 8, 1290-1309.
    • (2002) Angew. Chem., Int. Ed. , vol.8 , pp. 1290-1309
    • Herrmann, W.A.1
  • 26
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    • note
    • (c) The related NHC bearing palladium complex described in a and b, (IPr)-Pd(allyl)Cl, is now commercially available from Strem.
  • 27
    • 0032541260 scopus 로고    scopus 로고
    • For reviews on aryl amination see: (a) Hartwig, J. F. Angew. Chem., Int. Ed. 1998, 37, 2046-2067. (b) Muci, A. R.; Buchwald, S. L. Top. Curr. Chem. 2002, 219, 131-209.
    • (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 2046-2067
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  • 28
    • 0032541260 scopus 로고    scopus 로고
    • For reviews on aryl amination see: (a) Hartwig, J. F. Angew. Chem., Int. Ed. 1998, 37, 2046-2067. (b) Muci, A. R.; Buchwald, S. L. Top. Curr. Chem. 2002, 219, 131-209.
    • (2002) Top. Curr. Chem. , vol.219 , pp. 131-209
    • Muci, A.R.1    Buchwald, S.L.2
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    • note
    • The general biaryl product depicted in Scheme 2 is a proposed product as GCMS (EI) results indicate the presence of a peak at 197 (269 less the alkoxide moiety). This in conjunction with a stable species indicated by the GC peak lends indirect support to such a species. Further studies aimed at unequivocally identifying and characterizing this product are ongoing.


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