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b) J. J. Caroll, J. C. Weisshaar, P. E. M. Siegbahn, C. A. M. Wittborn, M. R. A. Blomberg, J. Phys. Chem. 1995, 99, 14388;
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c) M. Pavlov, M. R. A. Blomberg, P. E. M. Siegbahn, R. Wesendrup, C. Heinemann, H. Schwarz, J. Phys. Chem. A 1997, 101, 1567;
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Pavlov, M.1
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d) U. Achatz, M. Beyer, S. Joos, B. S. Fox, G. Niedner-Schatteburg, V. E. Bondybey, J. Phys. Chem. A 1999, 103, 8200.
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a) M. R. A. Blomberg, P. E. M. Siegbahn, M. Svensson, J. Phys. Chem. 1994, 98, 2062;
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c) M. Hendrickx, M. Ceulemans, L. Vanquickenborne, Chem. Phys. Lett. 1996, 257, 8.
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D. Schröder, M. Diefenbach, T. M. Klapötke, H. Schwarz, Angew. Chem. 1999, 111, 206; Angew. Chem. Int. Ed. 1999, 38, 137.
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D. Schröder, M. Diefenbach, T. M. Klapötke, H. Schwarz, Angew. Chem. 1999, 111, 206; Angew. Chem. Int. Ed. 1999, 38, 137.
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109
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For a review on small, thermochemically stable polycations, see: D. Schröder, H. Schwarz, J. Phys. Chem. A 1999, 103, 7385.
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J. Phys. Chem. A
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Schröder, D.1
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D. Schröder, J. N. Harvey, H. Schwarz, J. Phys. Chem. A 1998, 102, 3639.
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Schröder, D.1
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I. Kretzschmar, A. Fiedler, J. N. Harvey, D. Schröder, H. Schwarz, J. Phys. Chem. A 1997, 101, 6252.
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Kretzschmar, I.1
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112
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0141467270
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+ may serve as a good example as well as a convincing case for the crucial role adequate theoretical methods occasionally play in the interpretation of experimental findings; for details, see: a) J. Schwarz, C. Heinemann, D. Schröder, H. Schwarz, J. Hrušák, Helv. Chim. Acta 1996, 79, 1;
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(1996)
Helv. Chim. Acta
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Schwarz, J.1
Heinemann, C.2
Schröder, D.3
Schwarz, H.4
Hrušák, J.5
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113
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b) J. Schwarz, D. Schröder, H. Schwarz, C. Heinemann, J. Hrušák, Helv. Chim. Acta 1996, 79, 1110.
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(1996)
Helv. Chim. Acta
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Schwarz, J.1
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Schwarz, H.3
Heinemann, C.4
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115
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b) D. Schröder, H. Schwarz, Angew. Chem. 1995, 107, 2126; Angew. Chem. Int. Ed. Engl. 1995, 34, 1973.
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Schröder, D.1
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116
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b) D. Schröder, H. Schwarz, Angew. Chem. 1995, 107, 2126; Angew. Chem. Int. Ed. Engl. 1995, 34, 1973.
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Angew. Chem. Int. Ed. Engl.
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117
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12044249154
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See for example, the formally spin-forbidden reactions of some 3d-metal-oxide cations with hydrocarbons which occur at ambient temperature via surface crossings mediated by spin-orbit coupling ("two-state reactivity concept"): a) A. Fiedler, D. Schröder, S. Shaik, H. Schwarz, J. Am. Chem. Soc. 1994, 116, 10734;
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J. Am. Chem. Soc.
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Fiedler, A.1
Schröder, D.2
Shaik, S.3
Schwarz, H.4
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118
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84987350931
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b) S. Shaik, D. Danovich, A. Fiedler, D. Schröder, H. Schwarz, Helv. Chim. Acta 1995, 78, 1393;
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(1995)
Helv. Chim. Acta
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, pp. 1393
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Shaik, S.1
Danovich, D.2
Fiedler, A.3
Schröder, D.4
Schwarz, H.5
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119
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0031979212
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c) S. Shaik, M. Filatov, D. Schröder, H. Schwarz, Chem. Eur. J. 1998, 4, 193;
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Chem. Eur. J.
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Shaik, S.1
Filatov, M.2
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120
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0037742151
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d) D. Schröder, S. Shaik, H. Schwarz, Acc. Chem. Res. 2000, 33, 139;
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Acc. Chem. Res.
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Schröder, D.1
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123
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g) S. Shaik, S. P. de Visser, F. Ogliaro, H. Schwarz, D. Schröder, Curr. Opin. Chem. Biol. 2002, 6, 556;
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Curr. Opin. Chem. Biol.
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Shaik, S.1
De Visser, S.P.2
Ogliaro, F.3
Schwarz, H.4
Schröder, D.5
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125
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R. Wesendrup, D. Schröder, H. Schwarz, Angew. Chem. 1994, 106, 1232; Angew. Chem. Int. Ed. Engl. 1994, 33, 1174.
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Angew. Chem.
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Wesendrup, R.1
Schröder, D.2
Schwarz, H.3
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126
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33748236013
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R. Wesendrup, D. Schröder, H. Schwarz, Angew. Chem. 1994, 106, 1232; Angew. Chem. Int. Ed. Engl. 1994, 33, 1174.
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Angew. Chem. Int. Ed. Engl.
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-
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127
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0141578888
-
-
note
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c is the collision rate constant derived from capture theory.
-
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128
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36449004448
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and references therein
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T. Su, J. Chem. Phys. 1994, 100, 4703, and references therein.
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J. Chem. Phys.
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Su, T.1
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129
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+ (n = 0-2): a) M. Brönstrup, D. Schröder, I. Kretzschmar, H. Schwarz, J. N. Harvey, J. Am. Chem. Soc. 2001, 123, 142;
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(2001)
J. Am. Chem. Soc.
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Brönstrup, M.1
Schröder, D.2
Kretzschmar, I.3
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130
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0141802063
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personal communication
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b) D. K. Bohme, personal communication, 2002.
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Bohme, D.K.1
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131
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0000255558
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a) M. Aschi, M. Brönstrup, M. Diefenbach, J. N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. 1998, 110, 858; Angew. Chem. Int. Ed. 1998, 37, 829;
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Angew. Chem.
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Aschi, M.1
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132
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0344404192
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a) M. Aschi, M. Brönstrup, M. Diefenbach, J. N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. 1998, 110, 858; Angew. Chem. Int. Ed. 1998, 37, 829;
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133
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b) M. Diefenbach, M. Brönstrup, M. Aschi, D. Schroder, H. Schwarz, J. Am. Chem. Soc. 1999, 121, 10614;
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J. Am. Chem. Soc.
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Diefenbach, M.1
Brönstrup, M.2
Aschi, M.3
Schroder, D.4
Schwarz, H.5
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134
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0141690460
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note
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2) in particular, see: c) ref. [50];
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137
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0000683268
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f) F. Aguirre, J. Husband, C. J. Thompson, R. B. Metz, Chem. Phys. Lett. 2000, 318, 466.
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Chem. Phys. Lett.
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Aguirre, F.1
Husband, J.2
Thompson, C.J.3
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139
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0242669326
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b) K. Koszinowski, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 2003, 125, 3676;
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J. Am. Chem. Soc.
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Koszinowski, K.1
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0038759144
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M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 1999, 18, 1939.
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Organometallics
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Brönstrup, M.1
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143
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0001010889
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6, a new phosphorus allotrope, see: a) D. Schröder, H. Schwarz, M. Wulf, H. Sievers, P. Jutzi, M. Reiher, Angew. Chem. 1999, 111, 3723; Angew. Chem. Int. Ed. 1999, 38, 3513;
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Angew. Chem.
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Schröder, D.1
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Wulf, M.3
Sievers, H.4
Jutzi, P.5
Reiher, M.6
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144
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0344577862
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6, a new phosphorus allotrope, see: a) D. Schröder, H. Schwarz, M. Wulf, H. Sievers, P. Jutzi, M. Reiher, Angew. Chem. 1999, 111, 3723; Angew. Chem. Int. Ed. 1999, 38, 3513;
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Angew. Chem. Int. Ed.
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, pp. 3513
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147
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22444447301
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R. Wesendrup, H. Schwarz, Angew. Chem. 1995, 107, 2176; Angew. Chem. Int. Ed. Engl. 1995, 34, 2033, and references therein.
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(1995)
Angew. Chem.
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Wesendrup, R.1
Schwarz, H.2
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148
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33748230739
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and references therein
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R. Wesendrup, H. Schwarz, Angew. Chem. 1995, 107, 2176; Angew. Chem. Int. Ed. Engl. 1995, 34, 2033, and references therein.
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Angew. Chem. Int. Ed. Engl.
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-
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151
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0001336595
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H. H. Cornehl, C. Heinemann, D. Schröder, H. Schwarz, Organometallics 1995, 14, 992.
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(1995)
Organometallics
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Cornehl, H.H.1
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152
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0000951998
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C. Heinemann, H. H. Cornehl, H. Schwarz, J. Organomet. Chem. 1995, 501, 201.
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J. Organomet. Chem.
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, pp. 201
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Heinemann, C.1
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154
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0009710108
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b) H. H. Cornehl, C. Heinemann, J. Marçalo, A. Pires de Matos, H. Schwarz, Angew. Chem. 1996, 108, 950; Angew. Chem. Int. Ed. Engl. 1996, 35, 891;
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(1996)
Angew. Chem.
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Cornehl, H.H.1
Heinemann, C.2
Marçalo, J.3
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155
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33748231832
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b) H. H. Cornehl, C. Heinemann, J. Marçalo, A. Pires de Matos, H. Schwarz, Angew. Chem. 1996, 108, 950; Angew. Chem. Int. Ed. Engl. 1996, 35, 891;
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(1996)
Angew. Chem. Int. Ed. Engl.
, vol.35
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156
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0001200703
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c) H. H. Cornehl, R. Wesendrup, J. N. Harvey, H. Schwarz, J. Chem. Soc. Perkin Trans. 2 1997, 2283.
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(1997)
J. Chem. Soc. Perkin Trans. 2
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Cornehl, H.H.1
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Harvey, J.N.3
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157
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84985719622
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C. Heinemann, D. Schröder, H. Schwarz, Chem. Ber. 1994, 127, 1807.
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(1994)
Chem. Ber.
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, pp. 1807
-
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Heinemann, C.1
Schröder, D.2
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158
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0000596541
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a) C. Heinemann, N. Goldberg, I. C. Tornieporth-Oetting, T. M. Klapötke, H. Schwarz, Angew. Chem. 1995, 107, 225; Angew. Chem. Int. Ed. Engl. 1995, 34, 213;
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(1995)
Angew. Chem.
, vol.107
, pp. 225
-
-
Heinemann, C.1
Goldberg, N.2
Tornieporth-Oetting, I.C.3
Klapötke, T.M.4
Schwarz, H.5
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159
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33748498062
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a) C. Heinemann, N. Goldberg, I. C. Tornieporth-Oetting, T. M. Klapötke, H. Schwarz, Angew. Chem. 1995, 107, 225; Angew. Chem. Int. Ed. Engl. 1995, 34, 213;
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(1995)
Angew. Chem. Int. Ed. Engl.
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160
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0029969042
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b) H. Cornehl, G. Hornung, H. Schwarz, J. Am. Chem. Soc. 1996, 118, 9960;
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J. Am. Chem. Soc.
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Cornehl, H.1
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162
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0013399499
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d) D. Zhang, C. Zhang, C. Liu, J. Organomet. Chem. 2001, 640, 121;
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J. Organomet. Chem.
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Zhang, D.1
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163
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e) D. Zhang, C. Liu, S. Bi, J. Phys. Chem. A 2002, 106, 4153;
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J. Phys. Chem. A
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Zhang, D.1
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164
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0013412617
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f) D. Caraiman, G. K. Koyanagi, A. Cunje, A. C. Hopkinson, D. K. Bohme, Organometallics 2002, 21, 4293;
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(2002)
Organometallics
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Caraiman, D.1
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166
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0001595450
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a) C. Heinemann, H. H. Cornehl, D. Schröder, M. Dolg, H. Schwarz, Inorg. Chem. 1996, 35, 2463;
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Inorg. Chem.
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Heinemann, C.1
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b) H. H. Cornehl, R. Wesendrup, M. Diefenbach, H. Schwarz, Chem. Eur. J. 1997, 3, 1083.
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Chem. Eur. J.
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Cornehl, H.H.1
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