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Volumn 35, Issue 9, 1996, Pages 2463-2475

The CeO2+ Cation: Gas-Phase Reactivity and Electronic Structure

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EID: 0001595450     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951322k     Document Type: Article
Times cited : (75)

References (136)
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    • note
    • For reasons of clarity, electron transfer processes are not depicted in the schemes. Moreover, branching ratios are evaluated relative to all major processes. Electron transfer pathways are not included, since in all cases where they are observed they account to less than 5% of all ionic products.
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    • 2 from an aqueous matrix, accelerated to 8 keV kinetic energy and mass- as well as energy-selected using B(1) and E(1). He (80% transmission) was used to induce collisional activation of these ions and fragments were recorded by scanning B(2). For a description of the machine, see: (a) Srinivas, R., Sülze, D.; Weiske, T.; Schwarz, H. Int. J. Mass Spectrom. Ion Processes 1990, 107, 369. (b) Srinivas, R.; Sülze, D.; Koch, W.; DePuy, C. H.; Schwarz, H. J. Am. Chem Soc. 1991, 113, 5970.
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    • 2 from an aqueous matrix, accelerated to 8 keV kinetic energy and mass- as well as energy-selected using B(1) and E(1). He (80% transmission) was used to induce collisional activation of these ions and fragments were recorded by scanning B(2). For a description of the machine, see: (a) Srinivas, R., Sülze, D.; Weiske, T.; Schwarz, H. Int. J. Mass Spectrom. Ion Processes 1990, 107, 369. (b) Srinivas, R.; Sülze, D.; Koch, W.; DePuy, C. H.; Schwarz, H. J. Am. Chem Soc. 1991, 113, 5970.
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    • When small and weakly bound ligands are exchanged, this assumption does not necessarily apply: (a) Schwarz, J.; Heinemann, C.; Schwarz, H J. Phys. Chem. 1995, 99, 11405, (b) Heinemann, C.; Schwarz, J.; Schwarz, H. J. Phys. Chem., in press.
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    • in press
    • When small and weakly bound ligands are exchanged, this assumption does not necessarily apply: (a) Schwarz, J.; Heinemann, C.; Schwarz, H J. Phys. Chem. 1995, 99, 11405, (b) Heinemann, C.; Schwarz, J.; Schwarz, H. J. Phys. Chem., in press.
    • J. Phys. Chem.
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    • note
    • +.
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    • Gschneider, K. A., Eyring, L., Eds.; Elsevier: Amsterdam
    • (b) A comprehensive overview of electronic structure calculations for molecules containing lanthanide atoms is given in a recent review: Dolg, M.; Stoll, H. In Handbook on the Physics and Chemistry of Rare Earths; Gschneider, K. A., Eyring, L., Eds.; Elsevier: Amsterdam, 1995; Vol. 22.
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    • Ph.D. Thesis, Vrije Universiteit Amsterdam
    • (i) van Wezenbeek, E. M. Ph.D. Thesis, Vrije Universiteit Amsterdam 1992.
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    • 4).
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    • 4 complexes are available upon request from the authors, e-mail: schw0531@zrzsp5.chem.tu-berlin.de.
    • 4 complexes are available upon request from the authors, e-mail: schw0531@zrzsp5.chem.tu-berlin.de.
    • Heinemann, C.1    Cornehl, H.H.2    Schwarz, H.3


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