Gas-phase reactivity of lanthanide cations with fluorocarbons: C-F versus C-H and C-C bond activation

Journal of the American Chemical Society

Volumn 118, Issue 41, 1996, Pages 9960-9965

  Cornehl, Hans H ^a   Hornung, Georg ^a   Schwarz, Helmut ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

FLUOROCARBON; LANTHANIDE; METAL ION;

ARTICLE; DRUG ACTIVATION; MASS SPECTROMETRY; MOLECULAR DYNAMICS; THERMODYNAMICS;

EID: 0029969042     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja961343t     Document Type: Article

References (39)

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2. (a) Kiplinger, J. L.; Richmond, G. R.; Osterberg, C. E. Chem. Rev. 1994, 94, 373. Recent examples on homogeneous catalytic activation of C-F bonds by transition metal complexes: (b) Aizenberg, M.; Milstein, D. Science 1994, 265, 359. (c) Aizenberg, M.; Milstein, D. J. Am. Chem. Soc. 1995, 117, 8674.
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5. Recent reviews: (a) Armentrout, P. B. Annu. Rev. Phys. Chem. 1990, 41, 313. (b) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629. (c) Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121. (d) Eller, K. Coord. Chem. Rev. 1993, 123, 93. (e) Weisshaar, J. C. Acc. Chem. Res. 1993, 26, 213. (f) Freiser, B. S. Acc. Chem. Res. 1994, 27, 353.
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34. nLn-F)(n = 0-2) are reported with substantial error bars. However, they certainly serve to give orders of magnitude for these values and trends along the 4f row: Zmbov, K. F.; Margrave, J. L. In Mass Spectrometry in Inorganic Chemistry. Margrave, J. L., Ed. Adv. Chem. Ser. 1968, 72, 267.
35. +-F), Nd, 129 ± 14; Er, 127 ± 14.
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37. Second IE [eV] according to ref 13: La, 11.1; Ce, 10.8; Pr, 10.6; Nd, 10.7; Pm, 10.9; Sm, 11.1; Eu, 11.2; Gd, 12.1; Tb, 11.5; Dy, 11.7; Ho, 11.8; Er, 11.9; Tm, 12.1; Yb, 12.2; Lu, 13.9.
38. Electron transfer has been suggested earlier to account for C-F bond activation by rhodium and ruthenium complexes: (a) Blum, O.; Frolow, F.; Milstein, D. J. Chem. Soc., Chem. Commun. 1991, 258.
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