Oxo ligand as a reactivity switch in gas-phase ion chemistry of the Ianthanides

Journal of the Chemical Society. Perkin Transactions 2

Volumn , Issue 11, 1997, Pages 2283-2291

  Cornehl, Hans H ^a   Wesendrup, Ralf ^a   Harvey, Jeremy N ^a   Schwarz, Helmut ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001200703     PISSN: 03009580     EISSN: None     Source Type: Journal    
DOI: 10.1039/a703084c     Document Type: Article

References (59)

1. Recent reviews: (a) P. B. Armentrout, Ann. Rev. Phys. Chem., 1990, 41, 313; (b) J. A. Martinho Simões and J. L. Beauchamp, Chem. Rev., 1990, 90, 629; (c) K. Eller and H. Schwarz, Chem. Rev., 1991, 91, 1121; (d) K. Eller, Coord. Chem. Rev., 1993, 123, 93; (e) J. C. Weisshaar, Acc. Chem. Res., 1993, 26, 213; (f) B. S. Freiser, J. Mass Spectrom., 1996, 31, 703; (g) K. J. Fisher, I. G. Dance and G. D. Willett, Rapid Commun. Mass Spectrom., 1996, 10, 106.
2. Recent reviews: (a) P. B. Armentrout, Ann. Rev. Phys. Chem., 1990, 41, 313; (b) J. A. Martinho Simões and J. L. Beauchamp, Chem. Rev., 1990, 90, 629; (c) K. Eller and H. Schwarz, Chem. Rev., 1991, 91, 1121; (d) K. Eller, Coord. Chem. Rev., 1993, 123, 93; (e) J. C. Weisshaar, Acc. Chem. Res., 1993, 26, 213; (f) B. S. Freiser, J. Mass Spectrom., 1996, 31, 703; (g) K. J. Fisher, I. G. Dance and G. D. Willett, Rapid Commun. Mass Spectrom., 1996, 10, 106.
3. Recent reviews: (a) P. B. Armentrout, Ann. Rev. Phys. Chem., 1990, 41, 313; (b) J. A. Martinho Simões and J. L. Beauchamp, Chem. Rev., 1990, 90, 629; (c) K. Eller and H. Schwarz, Chem. Rev., 1991, 91, 1121; (d) K. Eller, Coord. Chem. Rev., 1993, 123, 93; (e) J. C. Weisshaar, Acc. Chem. Res., 1993, 26, 213; (f) B. S. Freiser, J. Mass Spectrom., 1996, 31, 703; (g) K. J. Fisher, I. G. Dance and G. D. Willett, Rapid Commun. Mass Spectrom., 1996, 10, 106.
4. Recent reviews: (a) P. B. Armentrout, Ann. Rev. Phys. Chem., 1990, 41, 313; (b) J. A. Martinho Simões and J. L. Beauchamp, Chem. Rev., 1990, 90, 629; (c) K. Eller and H. Schwarz, Chem. Rev., 1991, 91, 1121; (d) K. Eller, Coord. Chem. Rev., 1993, 123, 93; (e) J. C. Weisshaar, Acc. Chem. Res., 1993, 26, 213; (f) B. S. Freiser, J. Mass Spectrom., 1996, 31, 703; (g) K. J. Fisher, I. G. Dance and G. D. Willett, Rapid Commun. Mass Spectrom., 1996, 10, 106.
5. Recent reviews: (a) P. B. Armentrout, Ann. Rev. Phys. Chem., 1990, 41, 313; (b) J. A. Martinho Simões and J. L. Beauchamp, Chem. Rev., 1990, 90, 629; (c) K. Eller and H. Schwarz, Chem. Rev., 1991, 91, 1121; (d) K. Eller, Coord. Chem. Rev., 1993, 123, 93; (e) J. C. Weisshaar, Acc. Chem. Res., 1993, 26, 213; (f) B. S. Freiser, J. Mass Spectrom., 1996, 31, 703; (g) K. J. Fisher, I. G. Dance and G. D. Willett, Rapid Commun. Mass Spectrom., 1996, 10, 106.
6. Recent reviews: (a) P. B. Armentrout, Ann. Rev. Phys. Chem., 1990, 41, 313; (b) J. A. Martinho Simões and J. L. Beauchamp, Chem. Rev., 1990, 90, 629; (c) K. Eller and H. Schwarz, Chem. Rev., 1991, 91, 1121; (d) K. Eller, Coord. Chem. Rev., 1993, 123, 93; (e) J. C. Weisshaar, Acc. Chem. Res., 1993, 26, 213; (f) B. S. Freiser, J. Mass Spectrom., 1996, 31, 703; (g) K. J. Fisher, I. G. Dance and G. D. Willett, Rapid Commun. Mass Spectrom., 1996, 10, 106.
7. Recent reviews: (a) P. B. Armentrout, Ann. Rev. Phys. Chem., 1990, 41, 313; (b) J. A. Martinho Simões and J. L. Beauchamp, Chem. Rev., 1990, 90, 629; (c) K. Eller and H. Schwarz, Chem. Rev., 1991, 91, 1121; (d) K. Eller, Coord. Chem. Rev., 1993, 123, 93; (e) J. C. Weisshaar, Acc. Chem. Res., 1993, 26, 213; (f) B. S. Freiser, J. Mass Spectrom., 1996, 31, 703; (g) K. J. Fisher, I. G. Dance and G. D. Willett, Rapid Commun. Mass Spectrom., 1996, 10, 106.
8. (a) J. B. Schilling and J. L. Beauchamp, J. Am. Chem. Soc., 1988, 110, 15;
9. (b) L. S. Sunderlin and P. B. Armentrout, J. Am. Chem. Soc., 1989, 111, 3845;
10. (c) M. Azarro, S. Breton, M. Decouzon and S. Geribaldi, Int. J. Mass Spectrom. Ion Processes, 1993, 128, 1;
11. (d) C. Heinemann, D. Schröder and H. Schwarz, Chem. Ber., 1994, 127, 1807;
12. (e) W. W. Yin, A. G. Marshall, J. Marçalo and A. Pires de Matos, J. Am. Chem. Soc., 1994, 116, 8666;
13. (f) H. H. Cornehl, C. Heinemann, D. Schröder and H. Schwarz, Organometallics, 1995, 114, 992;
14. (g) J. Marçalo, A. Pires de Matos and W. J. Evans, Organometallics, 1996, 15, 345;
15. (h) H. H. Cornehl, G. Hornung and H. Schwarz, J. Am. Chem. Soc., 1996, 118, 9960;
16. (i) J. K. Gibson, J. Phys. Chem., 1996, 100, 15 688;
17. (j) H. H. Cornehl, R. Wesendrup, M. Diefenbach and H. Schwarz, Chem. Eur. J., 1997, 3, 1083;
18. (k) J. N. Harvey, D. Schröder, W. Koch, D. Danovich, S. Shaik and H. Schwarz, Chem. Phys. Lett., 1997, 273, 164.
19. Atomic data for the lanthanides are given in: W. C. Martin, R. Zalubas and L. Hagan. Atomic Energy Levels - The Rare Earth Elements, NSRDS-NBS 60, National Bureau of Standards, Washington DC, 1978.
20. (a) F. Bozon-Verduraz and A. Bensalem, J. Chem. Soc., Faraday Trans., 1994, 90, 653;
21. (b) J. Soria, A. Martínez-Arias and J. C. Conesa, J. Chem. Soc., Faraday Trans., 1995, 91, 1669.
22. (a) Handbook on the Physics and Chemistry of the Rare Earths, ed. K. A. Gschneider, Jr., and L. Eyring, Elsevier, Amsterdam, 1978 and proceeding volumes until 1995;
23. (b) Industrial Applications of Rare Earth Elements, ed. K. A. Gschneider, Jr., American Chemical Society, Washington, DC, 1981;
24. (c) Proceedings of the 2nd International Conference on f-Elements, University of Helsinki, August 1-6, 1994.
25. (a) D. J. Wilson, Polymer, 1993, 34, 3504;
26. (b) A. Proß, P. Marquart, K.-H. Reichert and T. Knauf, Angew. Makromol. Chem., 1993, 221, 89;
27. (c) D. J. Wilson, J. Polym. Sci., Polym. Chem., 1995, 33, 2505.
28. C. Heinemann, H. H. Cornehl, D. Schröder, M. Dolg and H. Schwarz, Inorg. Chem., 1996, 35, 2463.
29. (a) K. Eller and H. Schwarz, Int. J. Mass Spectrom. Ion Processes, 1989, 93, 243;
30. (b) K. Eller, W. Zummack and H. Schwarz, J. Am. Chem. Soc., 1990, 112, 621.
31. R. A. Forbes, F. H. Laukien and J. Wronka, Int. J. Mass Spectrom. Ion Processes, 1988, 83, 23.
32. T. Su and M. T. Bowers, Int. J. Mass Spectrom. Ion Phys., 1973, 12, 347.
33. (a) M = U: C. Heinemann, H. H. Cornehl and H. Schwarz, J. Organomet. Chem., 1995, 501, 201;
34. (b) M = W: P. Mourges, A. Ferhati, T. B. McMahon and G. Ohanessian, Organometallics, 1997, 16, 210;
35. (c) M = Rh, Ru: R. Wesendrup and H. Schwarz, Organometallics, 1997, 16, 621.
36. For a recent review on that topic, see: P. G. Cooks, J. S. Patrick, T. Kotiaho and S. A. McLuckey, Mass Spectrom. Rev., 1994, 13, 287, and references therein.
37. See, for example: (a) P. E. M. Siegbahn and M. R. A. Blomberg, J. Am. Chem. Soc., 1992, 114, 10 548; (b) C. L. Haynes, E. R. Fisher and R B. Armentrout, J. Phys. Chem., 1996, 100, 18 300; (c) M. C. Holthausen, Ph.D. Thesis, Technische Universität Berlin, D 83, 1996.
38. See, for example: (a) P. E. M. Siegbahn and M. R. A. Blomberg, J. Am. Chem. Soc., 1992, 114, 10 548; (b) C. L. Haynes, E. R. Fisher and R B. Armentrout, J. Phys. Chem., 1996, 100, 18 300; (c) M. C. Holthausen, Ph.D. Thesis, Technische Universität Berlin, D 83, 1996.
39. See, for example: (a) P. E. M. Siegbahn and M. R. A. Blomberg, J. Am. Chem. Soc., 1992, 114, 10 548; (b) C. L. Haynes, E. R. Fisher and R B. Armentrout, J. Phys. Chem., 1996, 100, 18 300; (c) M. C. Holthausen, Ph.D. Thesis, Technische Universität Berlin, D 83, 1996.
40. (a) Standard data are taken from: S. G. Lias, J. F. Liebman, R. D. Levin and S. A. Kafafi, NIST Standard Reference Database, Positive Ion Energetics, Version 2.01, January 1994;
41. -1 is used here, see: J. Berkowitz, G. B. Ellison and D. Gutman, J. Phys. Chem., 1994, 98, 2744.
42. (a) This value is commonly derived from the barrier for rotation around the inner C-C bond. See, for example: J. March, Advanced Organic Chemistry, Wiley, New York, 4th edn., 1992.
43. (b) For details, see: B. R. Arnold, V. Balaji and J. Michl, J. Am. Chem. Soc., 1990, 112, 1808, and references therein.
44. N. Goldberg, Cornell University, Ithaca, personal communication.
45. For a compilation of the available thermochemical data on lanthanide oxides, see: M. C. R. Cockett, L. Nyulászi, T. Vesprémi, T. G. Wright and J. M. Dyke, J. Electron Spectrosc. Relat. Phenom., 1991, 57, 373.
46. M. F. Ryan, A. Fiedler, D. Schröder and H. Schwarz, J. Am. Chem. Soc., 1995, 117, 2033.
47. II complexes, see: G. B. Deacon, G. D. Fallon, C. M. Forsyth, H. Schumann and R. Weimann, Chem. Ber., 1997, 130, 409;
48. 3] has been characterised: M. N. Bochkarev, I. L. Fedushkin, A. A. Fagin, T. V. Petrovskaya, J. W. Ziller, R. N. R. Broomhall-Dillard and W. J. Evans, Angew. Chem., Int. Ed. Engl., 1997, 36, 133.
49. For example, see: H. Schumann, J. A. Meese-Marktscheffel and L. Esser, Chem. Rev., 1995, 95, 865.
50. (a) A. Fiedler, D. Schröder, S. Shaik and H. Schwarz, J. Am. Chem. Soc., 1994, 116, 10 734;
51. (b) S. Shaik, D. Danovich, A. Fiedler, D. Schröder and H. Schwarz, Helv. Chim. Acta, 1995, 78, 1393.
52. A. Márquez, M. J. Capitán, J. A. Odriozola and J. F. Sanz, Int. J. Quant. Chem., 1994, 52, 653.
53. A comprehensive overview of electronic structure calculations for molecules containing lanthanide atoms is given in a recent review: M. Dolg and H. Stoll, in Handbook on the Physics and Chemistry of Rare Earths, ed. K. A. Gschneider, Jr., and L. Eyring, Elsevier, Amsterdam, 1995, vol. 22.
54. For excellent reviews on solution-phase reactions of cationic organic and organometallic electrophiles with unsaturated hydrocarbon nucleophiles, see: (a) H. Mayr, Angew. Chem., Int. Ed. Engl., 1990, 29, 1371; (b) H. Mayr and M. Patz, Angew. Chem., Int. Ed. Engl., 1994, 33, 938.
55. For excellent reviews on solution-phase reactions of cationic organic and organometallic electrophiles with unsaturated hydrocarbon nucleophiles, see: (a) H. Mayr, Angew. Chem., Int. Ed. Engl., 1990, 29, 1371; (b) H. Mayr and M. Patz, Angew. Chem., Int. Ed. Engl., 1994, 33, 938.
56. D. R. A. Ranatunga, Y. D. Hill and B. S. Freiser, Organometallics, 1996, 15, 1242.
57. R. J. Ackermann, E. G. Rauh and R. J. Thorn, J. Chem. Phys., 1976, 65, 1027, and references therein. These data are also compiled in ref. 14a.
58. See, for example: (a) R. C. Burnier, G. D. Byrd and B. S. Freiser, J. Am. Chem. Soc., 1981, 103, 4360; (b) M. A. Tolbert and J. L. Beauchamp, J. Phys. Chem., 1986, 90, 5015.
59. See, for example: (a) R. C. Burnier, G. D. Byrd and B. S. Freiser, J. Am. Chem. Soc., 1981, 103, 4360; (b) M. A. Tolbert and J. L. Beauchamp, J. Phys. Chem., 1986, 90, 5015.