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Volumn 125, Issue 36, 2003, Pages 11062-11064

Electrical conduction through linear porphyrin arrays

Author keywords

[No Author keywords available]

Indexed keywords

CONFORMATIONS; ELECTRIC CONDUCTANCE; ELECTRODES; ZINC;

EID: 0043234984     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0346429     Document Type: Article
Times cited : (80)

References (32)
  • 6
    • 0003404472 scopus 로고    scopus 로고
    • International Union of Pure and Applied Chemistry, Chemistry for the 21st Century Monographs; Blackwell Science: Cambridge, MA; Chapter 1
    • (f) Molecular Electronics; Jortner, J., Ratner, M. A., Eds.; International Union of Pure and Applied Chemistry, Chemistry for the 21st Century Monographs; Blackwell Science: Cambridge, MA, 1997; Chapter 1.
    • (1997) Molecular Electronics
    • Jortner, J.1    Ratner, M.A.2
  • 25
    • 0042290264 scopus 로고    scopus 로고
    • note
    • The directly linked orthogonal porphyrin arrays up to 128 Zn(II)porphyrins connected together can be prepared. But because of the relatively low solubility and the possibility of aggregation of longer arrays such as Z64 and Z128, Z48 was employed for electrical measurement in this study. For fused porphyrin arrays, Zn(II)porphyrin moieties can be fused up to 12 units (T12). But since the longer fused array is more vulnerable to oxidation reaction, T8 was employed in our measurements.
  • 32
    • 0041789104 scopus 로고    scopus 로고
    • note
    • The current at the voltage of 2.5 V for the fused porphyrin array is higher than that of the orthogonal porphyrin array by about 20 times, while the ratio of the length between the orthogonal and the fused porphyrin arrays is about 7. Consequently, the higher conductivity of the fused porphyrin array is not due to the length difference.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.