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note
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The directly linked orthogonal porphyrin arrays up to 128 Zn(II)porphyrins connected together can be prepared. But because of the relatively low solubility and the possibility of aggregation of longer arrays such as Z64 and Z128, Z48 was employed for electrical measurement in this study. For fused porphyrin arrays, Zn(II)porphyrin moieties can be fused up to 12 units (T12). But since the longer fused array is more vulnerable to oxidation reaction, T8 was employed in our measurements.
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note
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The current at the voltage of 2.5 V for the fused porphyrin array is higher than that of the orthogonal porphyrin array by about 20 times, while the ratio of the length between the orthogonal and the fused porphyrin arrays is about 7. Consequently, the higher conductivity of the fused porphyrin array is not due to the length difference.
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