Coupling reactions of α-bromoalkenyl phosphonates with aryl boronic acids and alkenyl borates

Organic Letters

Volumn 4, Issue 24, 2002, Pages 4241-4244

  Kobayashi, Yuichi ^a   William, Anthony D ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

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EID: 0041736591     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol020167s     Document Type: Article

References (43)

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31. 1H NMR spectra, which are given in Supporting Information. See ref 7a and the following refs for general information about coupling constants: (a) Kenyon, G. L.; Westheimer, F. H. J. Am. Chem. Soc. 1966, 88, 3557-3561.
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39. Prepared from the corresponding boronate ester (structure not shown) and MeLi (THF, 0°C, 10-15 min).
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42. 1H NMR spectroscopy and TLC analysis. Unfortunately, the stereochemistry of the trisubstituted olefin of the product could not be determined because of overlap of the signals.
43. 1H NMR spectra.