Rhodium-catalyzed hydrophosphorylation of terminal alkynes leading to highly selective formation of (E)-alkenylphosphonates: Complete reversal of regioselectivity to the palladium-catalyzed counterpart

Angewandte Chemie - International Edition

Volumn 40, Issue 10, 2001, Pages 1929-1932

  Zhao, Chang Qiu ^a   Han, Li Biao ^a   Goto, Midori ^a   Tanaka, Masato ^a  

^a NATL INST OF MAT AND CHEM RES   (Japan)

Author keywords

Alkynes; Homogeneous catalysis; Hyrophosphorylation; Phosphonate complexes; Rhodium

Indexed keywords

HYDROCARBONS; ORGANIC ACIDS; RHODIUM;

HYDROPHOSPHORYLATION;

CATALYSTS;

ALKYNE; PALLADIUM; PHOSPHONIC ACID DERIVATIVE; RHODIUM;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; ENVIRONMENTAL TEMPERATURE; PHOSPHORYLATION; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0035906931     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (35)