Synthesis and synthetic application of α-formylvinylphosphonates. Facile synthesis of phosphono-substituted heterocyclic compounds

Journal of Organic Chemistry

Volumn 65, Issue 14, 2000, Pages 4326-4332

  Kouno, Ryoji ^a   Tsubota, Terunobu ^a   Okauchi, Tatsuo ^a   Minami, Toru ^a  

^a KYUSHU INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ANION; HETEROCYCLIC COMPOUND; ISOCYANIC ACID DERIVATIVE; KETONE; PHOSPHONIC ACID DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; REACTION ANALYSIS; SYNTHESIS;

EID: 0034647772     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo000149t     Document Type: Article

References (40)

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29. 1H NMR analysis (see Experimental Section).
30. 1H NMR, its isolation was not attempted.
31. Diethyl 1-formylpentylphosphonate, which is hydrogenation product of 5k, was isolated in 37% yield along with 7k. The structure was identified by comparison of spectral data with those of an authentic sample.
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38. Although the compound 10 is composed of a single isomer, its stereochemical assignment was not made.
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40. For the synthesis of pyrazole from the reaction of α-oxo ketene dithioacetals with hydrazine, see, a review: Dieter, R. K. Tetrahedron 1986, 42, 3029. See also ref 15b.