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Unfortunately, using DDA it is not a direct method to assign a specific multipolar order to a given resonance structure. This is because the near field around the particle is not well described in this approximation. This has been pointed out before in ref 22.
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p and τ, we observed that for large dielectric functions convergency problems are always present. On the other hand, we have also performed calculations with semiconductor nanoparticles, and this problem of convergency is not observed. We have also found that if the number of dipoles are increased dramatically from 65 000 to half a million, then the optical properties converges.
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