-
2
-
-
1842394810
-
-
Patai S., Rappoport, Z., Eds.; John Wiley & Sons: New York, Chapter 14
-
(b) Smart, B. E. In The Chemistry of Functional Groups, Supplement D; Patai S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1983; Chapter 14.
-
(1983)
The Chemistry of Functional Groups, Supplement D
-
-
Smart, B.E.1
-
3
-
-
0010820910
-
-
For a comprehensive review of C-F activation by metal reagents, see: Kiplinger, J. L.; Richmond, T. G.; Osterberg, C. E. Chem. Rev. 1994, 94, 373-431.
-
(1994)
Chem. Rev.
, vol.94
, pp. 373-431
-
-
Kiplinger, J.L.1
Richmond, T.G.2
Osterberg, C.E.3
-
7
-
-
37049089150
-
-
(a) Jones, W. D.; Partridge, M. G.; Perutz, R. N. J. Chem. Soc., Chem. Commun. 1991, 264-266.
-
J. Chem. Soc., Chem. Commun.
, vol.1991
, pp. 264-266
-
-
Jones, W.D.1
Partridge, M.G.2
Perutz, R.N.3
-
8
-
-
0001082986
-
-
(b) Belt, S. T.; Helliwell M.; Jones W. D.; Partridge, M. G.; Perutz, R. N. J. Am. Chem. Soc. 1993, 115, 1429-1440.
-
(1993)
J. Am. Chem. Soc.
, vol.115
, pp. 1429-1440
-
-
Belt, S.T.1
Helliwell, M.2
Jones, W.D.3
Partridge, M.G.4
Perutz, R.N.5
-
10
-
-
37049089151
-
-
Blum, O.; Frolow, F.; Milstein, D. J. Chem. Soc., Chem. Commun. 1991, 258-259.
-
(1991)
J. Chem. Soc., Chem. Commun.
, pp. 258-259
-
-
Blum, O.1
Frolow, F.2
Milstein, D.3
-
12
-
-
4243181433
-
-
Bach, I.; Pörschke; Goddard, R.; Kopiske, C.; Krüger, C.; Rufinska, A.; Seevogel, K. Organometallics 1996, 15, 4959-4966.
-
(1996)
Organometallics
, vol.15
, pp. 4959-4966
-
-
Bach, I.1
Pörschke2
Goddard, R.3
Kopiske, C.4
Krüger, C.5
Rufinska, A.6
Seevogel, K.7
-
13
-
-
0001105082
-
-
Whittlesey, M. K.; Perutz, R. N.; Moore, M. H. J. Chem. Soc., Chem. Commun. 1996, 787-788.
-
(1996)
J. Chem. Soc., Chem. Commun.
, pp. 787-788
-
-
Whittlesey, M.K.1
Perutz, R.N.2
Moore, M.H.3
-
14
-
-
0002299883
-
-
Whittlesey, M. K.; Perutz, R. N.; Greener, B.; Moore, M. H. J. Chem. Soc., Chem. Commun. 1997, 187-188.
-
(1997)
J. Chem. Soc., Chem. Commun.
, pp. 187-188
-
-
Whittlesey, M.K.1
Perutz, R.N.2
Greener, B.3
Moore, M.H.4
-
15
-
-
1842351209
-
-
Selmeczy, A. D.; Jones, W. D.; Partridge, M. G.; Perutz, R. N. Organometallics 1994, 13, 385-396.
-
(1994)
Organometallics
, vol.13
, pp. 385-396
-
-
Selmeczy, A.D.1
Jones, W.D.2
Partridge, M.G.3
Perutz, R.N.4
-
17
-
-
1842273372
-
-
note
-
HF = 120.5 Hz) at δ 18.44. A mixture of pyridine·HF and fluoride ion shows a broad resonance at ∼δ 14, which moves with the relative amounts of the two components.
-
-
-
-
20
-
-
33947334972
-
-
(a) Walling, C.; Cooley, J. H.; Ponaras, A. A.; Racah, E. J. J. Am. Chem. Soc. 1966, 88, 5361-5363.
-
(1966)
J. Am. Chem. Soc.
, vol.88
, pp. 5361-5363
-
-
Walling, C.1
Cooley, J.H.2
Ponaras, A.A.3
Racah, E.J.4
-
23
-
-
0038095095
-
-
(d) Kinney, R. J.; Jones, W. D.; Bergman, R. G. J. Am. Chem. Soc. 1978, 100, 635-637.
-
(1978)
J. Am. Chem. Soc.
, vol.100
, pp. 635-637
-
-
Kinney, R.J.1
Jones, W.D.2
Bergman, R.G.3
-
24
-
-
0344887064
-
-
Fluoride is known to be an excellent base in nonprotic solvents, some 12 orders of magnitude better in DMSO than in water. See: Bordwell, F. G. Acc. Chem. Res. 1988, 21, 456-463.
-
(1988)
Acc. Chem. Res.
, vol.21
, pp. 456-463
-
-
Bordwell, F.G.1
-
25
-
-
1842303297
-
-
Hudlicky, M., Rappoport, Z., Eds.; ACS Monograph 187; American Chemical Society: Washington, DC
-
(a) Smart, B. E. In Chemistry of Organic Fluorine Compounds II; Hudlicky, M., Rappoport, Z., Eds.; ACS Monograph 187; American Chemical Society: Washington, DC, 1995; pp 996-997.
-
(1995)
Chemistry of Organic Fluorine Compounds
, vol.2
, pp. 996-997
-
-
Smart, B.E.1
-
27
-
-
0007064982
-
-
(c) Rodionov, P. P.; Osina, O. I.; Platonov, V. E.; Yakobson, G. G. Bull. Soc. Chim. Fr. 1986, 6, 986-992.
-
(1986)
Bull. Soc. Chim. Fr.
, vol.6
, pp. 986-992
-
-
Rodionov, P.P.1
Osina, O.I.2
Platonov, V.E.3
Yakobson, G.G.4
-
28
-
-
1842359061
-
-
note
-
F radical. This radical could then recombine with the metal radical to generate the observed metal product. Any radicals formed, however, would have to recombine within the radical cage (vide infra).
-
-
-
-
30
-
-
0001767884
-
-
5H ligand. See: Jones, W. D.; Kuykendall, V. L.; Selmeczy, A. D. Organometallics 1991, 10, 1577-1586.
-
(1991)
Organometallics
, vol.10
, pp. 1577-1586
-
-
Jones, W.D.1
Kuykendall, V.L.2
Selmeczy, A.D.3
-
31
-
-
0001067106
-
-
Hughes, R. P.; Lindler, D. C.; Rheingold, A. L.; Yap, G. P. A. Organometallics 1996, 15, 5678-5686.
-
(1996)
Organometallics
, vol.15
, pp. 5678-5686
-
-
Hughes, R.P.1
Lindler, D.C.2
Rheingold, A.L.3
Yap, G.P.A.4
-
32
-
-
0000279807
-
-
Hintermann, S.; Pregosin, P. S.; Ruegger, H.; Clark, H. C. J. Organomet. Chem. 1992, 435, 225-234.
-
(1992)
J. Organomet. Chem.
, vol.435
, pp. 225-234
-
-
Hintermann, S.1
Pregosin, P.S.2
Ruegger, H.3
Clark, H.C.4
-
34
-
-
0002779335
-
-
(b) Symons, M. C. R.; Selby, R. C.; Smith, I. G.; Bratt, S. W. Chem. Phys. Lett. 1977, 48, 100-102.
-
(1977)
Chem. Phys. Lett.
, vol.48
, pp. 100-102
-
-
Symons, M.C.R.1
Selby, R.C.2
Smith, I.G.3
Bratt, S.W.4
-
35
-
-
0001358949
-
-
Ryan, O. B.; Tilset, M.; Parker, V. D. J. Am. Chem. Soc. 1990, 112, 2618-2626.
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 2618-2626
-
-
Ryan, O.B.1
Tilset, M.2
Parker, V.D.3
-
36
-
-
0001447240
-
-
Marsella, J. A.; Gilicinski, A. G.; Coughlin, A. M.; Pez, G. P. J. Org. Chem. 1992, 57, 2856-2860.
-
(1992)
J. Org. Chem.
, vol.57
, pp. 2856-2860
-
-
Marsella, J.A.1
Gilicinski, A.G.2
Coughlin, A.M.3
Pez, G.P.4
-
37
-
-
1842357178
-
-
note
-
17
-
-
-
-
38
-
-
0001340676
-
-
Kirtley, S. W.; Andrews, M. A.; Bau, R.; Grynkewich, G. W.; Marks, T. J.; Tipton, D. L.; Whittlesey, B. R. J. Am. Chem. Soc. 1977, 99, 7154-7162.
-
(1977)
J. Am. Chem. Soc.
, vol.99
, pp. 7154-7162
-
-
Kirtley, S.W.1
Andrews, M.A.2
Bau, R.3
Grynkewich, G.W.4
Marks, T.J.5
Tipton, D.L.6
Whittlesey, B.R.7
-
39
-
-
37049110777
-
-
Isobe, K.; Bailey, P. M.; Maitlis, P. M. J. Chem. Soc., Dalt. Trans. 1981, 2003.
-
(1981)
J. Chem. Soc., Dalt. Trans.
, pp. 2003
-
-
Isobe, K.1
Bailey, P.M.2
Maitlis, P.M.3
-
40
-
-
1842274386
-
-
D.Phil. Thesis, University of York, U.K.
-
Partridge, M. G. D.Phil. Thesis, University of York, U.K., 1992.
-
(1992)
-
-
Partridge, M.G.1
-
41
-
-
62249149504
-
-
Pyridinium tetraphenylborate was prepared following the general methodology developed by Wittig and co-workers: (a) Wittig, G.; Raff, P. Justus Liebigs Ann. Chem. 1951, 573, 195-209. (b) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Justus Liebigs Ann. Chem. 1949, 563, 110-126. (c) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Chem. Ber. 1955, 88, 962-976.
-
(1951)
Justus Liebigs Ann. Chem.
, vol.573
, pp. 195-209
-
-
Wittig, G.1
Raff, P.2
-
42
-
-
2642612918
-
-
Pyridinium tetraphenylborate was prepared following the general methodology developed by Wittig and co-workers: (a) Wittig, G.; Raff, P. Justus Liebigs Ann. Chem. 1951, 573, 195-209. (b) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Justus Liebigs Ann. Chem. 1949, 563, 110-126. (c) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Chem. Ber. 1955, 88, 962-976.
-
(1949)
Justus Liebigs Ann. Chem.
, vol.563
, pp. 110-126
-
-
Wittig, G.1
Keicher, G.2
Ruckert, A.3
Raff, P.4
-
43
-
-
0010851451
-
-
Pyridinium tetraphenylborate was prepared following the general methodology developed by Wittig and co-workers: (a) Wittig, G.; Raff, P. Justus Liebigs Ann. Chem. 1951, 573, 195-209. (b) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Justus Liebigs Ann. Chem. 1949, 563, 110-126. (c) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Chem. Ber. 1955, 88, 962-976.
-
(1955)
Chem. Ber.
, vol.88
, pp. 962-976
-
-
Wittig, G.1
Keicher, G.2
Ruckert, A.3
Raff, P.4
-
44
-
-
0003872738
-
-
The Kynoch Press: Birmingham, England, Tables 2.2B and 2.3.1
-
o, f′, and f″: Cromer, D. T.; Waber, J. T. International Tables for X-ray Crystallography; The Kynoch Press: Birmingham, England, 1974; Vol IV, Tables 2.2B and 2.3.1.
-
(1974)
International Tables for X-ray Crystallography
, vol.4
-
-
Cromer, D.T.1
Waber, J.T.2
-
45
-
-
1842317557
-
-
note
-
It has been noted that the integration program SAINT produces cell constant errors that are unreasonably small, since systematic error is not included. More reasonable errors might be estimated at 10x the listed values.
-
-
-
-
46
-
-
1842355228
-
-
note
-
2].
-
-
-
-
47
-
-
33845470265
-
-
Cox, D. P.; Terpinski, J.; Lawrynowicz, W. J. Org. Chem. 1984, 49, 3216-3219.
-
(1984)
J. Org. Chem.
, vol.49
, pp. 3216-3219
-
-
Cox, D.P.1
Terpinski, J.2
Lawrynowicz, W.3
|