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Volumn 119, Issue 33, 1997, Pages 7734-7742

Mechanism of carbon-fluorine bond activation by (C5Me5)Rh(PMe3)H2

Author keywords

[No Author keywords available]

Indexed keywords

FLUORIDE ION; ORGANOMETALLIC COMPOUND; PERFLUORO COMPOUND;

EID: 0030963988     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja970723r     Document Type: Article
Times cited : (148)

References (47)
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    • note
    • HF = 120.5 Hz) at δ 18.44. A mixture of pyridine·HF and fluoride ion shows a broad resonance at ∼δ 14, which moves with the relative amounts of the two components.
  • 24
    • 0344887064 scopus 로고
    • Fluoride is known to be an excellent base in nonprotic solvents, some 12 orders of magnitude better in DMSO than in water. See: Bordwell, F. G. Acc. Chem. Res. 1988, 21, 456-463.
    • (1988) Acc. Chem. Res. , vol.21 , pp. 456-463
    • Bordwell, F.G.1
  • 25
    • 1842303297 scopus 로고
    • Hudlicky, M., Rappoport, Z., Eds.; ACS Monograph 187; American Chemical Society: Washington, DC
    • (a) Smart, B. E. In Chemistry of Organic Fluorine Compounds II; Hudlicky, M., Rappoport, Z., Eds.; ACS Monograph 187; American Chemical Society: Washington, DC, 1995; pp 996-997.
    • (1995) Chemistry of Organic Fluorine Compounds , vol.2 , pp. 996-997
    • Smart, B.E.1
  • 28
    • 1842359061 scopus 로고    scopus 로고
    • note
    • F radical. This radical could then recombine with the metal radical to generate the observed metal product. Any radicals formed, however, would have to recombine within the radical cage (vide infra).
  • 37
    • 1842357178 scopus 로고    scopus 로고
    • note
    • 17
  • 40
    • 1842274386 scopus 로고
    • D.Phil. Thesis, University of York, U.K.
    • Partridge, M. G. D.Phil. Thesis, University of York, U.K., 1992.
    • (1992)
    • Partridge, M.G.1
  • 41
    • 62249149504 scopus 로고
    • Pyridinium tetraphenylborate was prepared following the general methodology developed by Wittig and co-workers: (a) Wittig, G.; Raff, P. Justus Liebigs Ann. Chem. 1951, 573, 195-209. (b) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Justus Liebigs Ann. Chem. 1949, 563, 110-126. (c) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Chem. Ber. 1955, 88, 962-976.
    • (1951) Justus Liebigs Ann. Chem. , vol.573 , pp. 195-209
    • Wittig, G.1    Raff, P.2
  • 42
    • 2642612918 scopus 로고
    • Pyridinium tetraphenylborate was prepared following the general methodology developed by Wittig and co-workers: (a) Wittig, G.; Raff, P. Justus Liebigs Ann. Chem. 1951, 573, 195-209. (b) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Justus Liebigs Ann. Chem. 1949, 563, 110-126. (c) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Chem. Ber. 1955, 88, 962-976.
    • (1949) Justus Liebigs Ann. Chem. , vol.563 , pp. 110-126
    • Wittig, G.1    Keicher, G.2    Ruckert, A.3    Raff, P.4
  • 43
    • 0010851451 scopus 로고
    • Pyridinium tetraphenylborate was prepared following the general methodology developed by Wittig and co-workers: (a) Wittig, G.; Raff, P. Justus Liebigs Ann. Chem. 1951, 573, 195-209. (b) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Justus Liebigs Ann. Chem. 1949, 563, 110-126. (c) Wittig, G.; Keicher, G.; Ruckert, A.; Raff, P. Chem. Ber. 1955, 88, 962-976.
    • (1955) Chem. Ber. , vol.88 , pp. 962-976
    • Wittig, G.1    Keicher, G.2    Ruckert, A.3    Raff, P.4
  • 45
    • 1842317557 scopus 로고    scopus 로고
    • note
    • It has been noted that the integration program SAINT produces cell constant errors that are unreasonably small, since systematic error is not included. More reasonable errors might be estimated at 10x the listed values.
  • 46
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    • note
    • 2].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.