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Volumn 18, Issue 19, 1999, Pages 3851-3858

Ferrocene in Conjugation with a Fischer Carbene: Synthesis, NLO, and Electrochemical Behavior of a Novel Organometallic Push-Pull System

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EID: 0000326694     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990257+     Document Type: Article
Times cited : (123)

References (47)
  • 12
    • 0003947851 scopus 로고    scopus 로고
    • Kajzar, F., Agranovich, V. M., Lee, C. Y., Eds.; NATO ASI Series; Kluwer: The Netherlands
    • (e) Ledoux, I.; Brasselet, S.; Dhenaut, C.; Zyss, J. In Photoactive Organic Materials; Kajzar, F., Agranovich, V. M., Lee, C. Y., Eds.; NATO ASI Series; Kluwer: The Netherlands, 1996; Vol. 9.
    • (1996) Photoactive Organic Materials , vol.9
    • Ledoux, I.1    Brasselet, S.2    Dhenaut, C.3    Zyss, J.4
  • 20
    • 0000607587 scopus 로고
    • 5 moeity. For previous use of Fischer carbene complexes as NLO materials, see: (a) Maiorana, S.; Papagni, A.; Licandro, E.; Persoons, A.; Clays, K.; Houbrechts, S.; Porzio, W. Gazz. Chim. Ital. 1995, 125, 377. (b) Fischer, H.; Podschadly, O.; Roth, G.; Herminghaus, S.; Klewitz, S.; Heck, J.; Houbrechts, S.; Meyer, T. J. Organomet. Chem. 1997, 541, 321. (c) Roth, G.; Fischer, H.; Meyer-Friendrichsen, T.; Heck, J.; Houbrechts, S.; Persoons, A. Organometallics 1998, 17, 1511.
    • (1995) Gazz. Chim. Ital. , vol.125 , pp. 377
    • Maiorana, S.1    Papagni, A.2    Licandro, E.3    Persoons, A.4    Clays, K.5    Houbrechts, S.6    Porzio, W.7
  • 21
    • 0031571434 scopus 로고    scopus 로고
    • 5 moeity. For previous use of Fischer carbene complexes as NLO materials, see: (a) Maiorana, S.; Papagni, A.; Licandro, E.; Persoons, A.; Clays, K.; Houbrechts, S.; Porzio, W. Gazz. Chim. Ital. 1995, 125, 377. (b) Fischer, H.; Podschadly, O.; Roth, G.; Herminghaus, S.; Klewitz, S.; Heck, J.; Houbrechts, S.; Meyer, T. J. Organomet. Chem. 1997, 541, 321. (c) Roth, G.; Fischer, H.; Meyer-Friendrichsen, T.; Heck, J.; Houbrechts, S.; Persoons, A. Organometallics 1998, 17, 1511.
    • (1997) J. Organomet. Chem. , vol.541 , pp. 321
    • Fischer, H.1    Podschadly, O.2    Roth, G.3    Herminghaus, S.4    Klewitz, S.5    Heck, J.6    Houbrechts, S.7    Meyer, T.8
  • 22
    • 0000923785 scopus 로고    scopus 로고
    • 5 moeity. For previous use of Fischer carbene complexes as NLO materials, see: (a) Maiorana, S.; Papagni, A.; Licandro, E.; Persoons, A.; Clays, K.; Houbrechts, S.; Porzio, W. Gazz. Chim. Ital. 1995, 125, 377. (b) Fischer, H.; Podschadly, O.; Roth, G.; Herminghaus, S.; Klewitz, S.; Heck, J.; Houbrechts, S.; Meyer, T. J. Organomet. Chem. 1997, 541, 321. (c) Roth, G.; Fischer, H.; Meyer-Friendrichsen, T.; Heck, J.; Houbrechts, S.; Persoons, A. Organometallics 1998, 17, 1511.
    • (1998) Organometallics , vol.17 , pp. 1511
    • Roth, G.1    Fischer, H.2    Meyer-Friendrichsen, T.3    Heck, J.4    Houbrechts, S.5    Persoons, A.6
  • 24
    • 0041475272 scopus 로고
    • Dotz, K. H., Fischer, H., Hofman, P., Kreissel, F. R., Schubert, U., Weiss, K., Eds.; Verlag-Chemie: Weinheim
    • (a) Hofman, P. In Electronic Structures of Transition Metal Carbene Complexes; Dotz, K. H., Fischer, H., Hofman, P., Kreissel, F. R., Schubert, U., Weiss, K., Eds.; Verlag-Chemie: Weinheim, 1983.
    • (1983) Electronic Structures of Transition Metal Carbene Complexes
    • Hofman, P.1
  • 28
    • 36749107537 scopus 로고
    • 0| values for 1a-d as 9.03, 29.77, 54.15, and 100.78, respectively. Similar values obtained for 2a-c are 6.08, 21.05, and 45.35, respectively.
    • (1977) J. Chem. Phys. , vol.67 , pp. 446
    • Oudar, J.L.1
  • 31
    • 85021620581 scopus 로고
    • (c) In all the compounds resonance enhancement contributes a part to β. The factors governing the resonance enhancement are not understood thoroughly. It is known that the stronger acceptor does not necessarily lead to the largest nonlinearities (see: Marder, S. R.; Gorman, G. B.; Tiemann B. G.; Cheng, L. T. J. Am. Chem. Soc. 1993, 115, 3006); rather an optimal degree of bond length alteration in a polyene bridge exhibits the largest β (see: Gorman, G. B.; Marder, S. R. Proc. Natl. Acad. Sci. U.S.A. 1993, 90, 11297).
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 3006
    • Marder, S.R.1    Gorman, G.B.2    Tiemann, B.G.3    Cheng, L.T.4
  • 32
    • 0027363444 scopus 로고
    • (c) In all the compounds resonance enhancement contributes a part to β. The factors governing the resonance enhancement are not understood thoroughly. It is known that the stronger acceptor does not necessarily lead to the largest nonlinearities (see: Marder, S. R.; Gorman, G. B.; Tiemann B. G.; Cheng, L. T. J. Am. Chem. Soc. 1993, 115, 3006); rather an optimal degree of bond length alteration in a polyene bridge exhibits the largest β (see: Gorman, G. B.; Marder, S. R. Proc. Natl. Acad. Sci. U.S.A. 1993, 90, 11297).
    • (1993) Proc. Natl. Acad. Sci. U.S.A. , vol.90 , pp. 11297
    • Gorman, G.B.1    Marder, S.R.2
  • 36
    • 85088002904 scopus 로고    scopus 로고
    • note
    • 16 Compared to the W complex, 1b, the Cr complex 2b shows higher reversibility of the second-step oxidation reaction. This difference in chemical reversibility is also observed for the authentic carbene complexes.


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