Hyper-Rayleigh Scattering in Isotropic Solution

Accounts of Chemical Research

Volumn 31, Issue 10, 1998, Pages 675-683

  Hendrickx, Eric ^a,b,c   Clays, Koen ^a,c   Persoons, André ^a,b,d,e  

^a UNIVERSITY OF LEUVEN   (Belgium)

^b UNIVERSITY OF ARIZONA   (United States)

^c Fund for Scientific Research   (United States)

^d MAX PLANCK INSTITUTE FOR BIOPHYSICAL CHEMISTRY   (Germany)

^e Universities of Ghent and Brussels   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000384625     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar960233o     Document Type: Article

References (49)

1. Boyd, R. W. Nonlinear optics; Academic: San Diego, 1992.
2. Prasad, N. P.; Williams, D. J. Introduction to Nonlinear Optical Effects in Molecules and Polymers; Wiley: New York, 1991.
3. Levine, B. F.; Bethea, C. G. Second and third-order hyperpolarizabilities of organic molecules. J. Chem. Phys. 1975, 63, 2666.
4. Clays, K.; Persoons, A. HRS in solution. Phys. Rev. Lett. 1991, 66, 2980.
5. Clays, K.; Persoons, A. HRS in solution. Rev. Sci. Instrum. 1992, 63, 3285.
6. Clays, K.; Persoons, A.; De Maeyer, L. HRS in solution. Adv. Chem. Phys. 1994, 85 (III), 455.
7. Terhune, R. W.; Maker, P. D.; Savage, C. M. Measurements of nonlinear light scattering. Phys. Rev. Lett. 1965, 14, 681.
8. Cyvin, S. J.; Rauch, J. E.; Decius, J. C. Theory of hyper-Raman effects: Selection rules and depolarization ratios for second-order polarizability. J. Chem. Phys. 1965, 43, 4083.
9. Bersohn, R.; Pao, Y. H.; Frish, H. L. Double-quantum light scattering by molecules. J. Chem. Phys. 1966, 45, 3484.
10. Kaatz, P.; Shelton, D. P. Polarized HRS measurements of nonlinear optical chromophores. J. Chem. Phys. 1996, 105, 3918.
11. Kaatz, P.; Shelton, D. P. Spectral measurements of HRS. Rev. Sci. Instrum. 1996, 67, 1438.
12. Morrison, I. D.; Denning, R. G.; Laidlaw, W. M.; Stammers, M. A. Measurement of first hyperpolarizabilities by HRS. Rev. Sci. Instrum. 1996, 67, 1445.
13. Kauranen, M.; Persoons, A. Theory of polarization measurements of second-order nonlinear light scattering. J. Chem. Phys. 1996, 104, 3445.
14. Verbiest, T.; Hendrickx, E.; Persoons, A.; Clays, K. Measurements of molecular hyperpolarizabilities using HRS. Proc. Soc. Photo-Opt. Instrum. Eng. 1992, 1775, 206.
15. Hendrickx, E.; Dehu, C.; Clays, K.; Brédas, J. L.; Persoons, A. In Polymers for Second-Order Nonlinear Optics; ACS Symposium Series 601; American Chemical Society: Washington, DC, 1994, p 82.
16. Stadler, S.; Bourhill, G.; Bräuchle, C. Problems associated with HRS as a means to determine the second-order polarizability of organic chromophores. J. Phys. Chem. 1996, 100, 6927.
17. Pauley, M. A.; Guan, H.-W.; Wang, C. H.; Jen, A. K.-Y. Determination of first hyperpolarizability of nonlinear optical chromophores by second harmonic scattering using an external reference. J. Chem. Phys. 1996, 104, 7821.
18. Maker, P. D. Spectral broadening of elastic second-harmonic light scattering in liquids. Phys. Rev. A 1970, 1, 923.
19. 4 due to rotational motions and the intermolecular interactions. J. Chem. Phys. 1988, 89, 1892.
20. Kielich, S.; Lalanne, J. R.; Martin, F. B. Double-photon light scattering by liquids having centrosymmetric molecules. Phys. Rev. Lett. 1971, 26, 1295.
21. Neddersen, J. P.; Mounter, S. A.; Bostick, J. M.; Johnson, C. K. Nonresonant hyper-Raman and HRS in benzene and pyridine. J. Chem. Phys. 1989, 90, 4719.
22. Flipse, M. C.; de Jonge, R.; Woudenberg, R. H.; Marsman, A. W.; van Walree, C. A.; Jenneskens, L. W. The determination of β using HRS: a caveat. Chem. Phys. Lett. 1995, 245, 297.
23. Stadler, S.; Dietrich, R.; Bourhill, G.; Bräuchle, Ch. Long-wavelength first hyperpolarizability measurements by HRS. Opt. Lett. 1996, 21, 251.
24. Song, N. W.; Kang, T. I.; Jeoung, S. C.; Jeon, S. J.; Cho, B. R.; Kim, D. Improved method for measuring β of organic NLO materials in solution by using the HRS technique. Chem. Phys. Lett. 1996, 261, 307.
25. Clays, K.; Persoons, A. HRS in solution with tunable femtosecond continuous-wave laser source. Rev. Sci. Instrum. 1994, 65, 2190.
26. Noordman, O. F. J.; van Hulst, N. F. Time-resolved HRS: Measuring β of fluorescent molecules. Chem. Phys. Lett. 1996, 253, 145.
27. Olbrechts, G.; Clays, K.; Persoons, A. High-frequency demodulation of multiphoton fluorescence in HRS submitted for publication in Rev. Sci. Instrum. 1998, 69 (6), 2233-2241.
28. Kanis, D. R.; Ratner, M. A.; Marks, T. J. Design and construction of molecular assemblies with large second-order optical nonlinearities. Quant. Chem. Asp. Chem. Rev. 1994, 94, 195.
29. Heesink, G. J. T.; Ruiter, A. G. T.; van Hulst, N. F.; Bölger, B. Determination of hyperpolarizability tensor components by depolarized HRS. Phys. Rev. Lett. 1993, 71, 999.
30. Stähelin, M.; Burland, D. M.; Rice, J. E. Solvent dependence of the second-order hyperpolarizability in p-nitroaniline. Chem. Phys. Lett. 1992, 191, 245.
31. Oesterhelt, D.; Bräuchle, C.; Hampp, N. Bacteriorhodopsin: a biological material for information processing. Q. Rev. Biophys. 1991, 24, 425.
32. Clays, K.; Hendrickx, E.; Triest, M.; Verbiest, T.; Persoons, A.; Dehu, C.; Brédas, J. L. Nonlinear optical properties of proteins measured by HRS in solution. Science 1993, 262, 1419.
33. Hendrickx, E.; Clays, K.; Persoons, A.; Dehu, C.; Brédas, J. L. The bacteriorhodopsin chromophore retinal and derivatives: An experimental and theoretical investigation of the second-order optical properties. J. Am. Chem. Soc. 1995, 117, 3547.
34. Dehu, C.; Meyers, F.; Hendrickx, E.; Clays, K.; Persoons, A.; Marder, S. R.; Brédas, J. L. Solvent effects on the second-order nonlinear optical response of π-conjugated molecules: A combined evaluation through self-consistent reaction field calculations and HRS measurements. J. Am. Chem. Soc. 1995, 117, 10127.
35. Marder, S. R.; Gorman, C. B.; Meyers, F.; Perry, J. W.; Bourhill, G.; Brédas, J. L.; Pierce, B. M. A unified description of linear and nonlinear polarization in organic polymethine dyes. Science 1994, 265, 632.
36. Whittall, I. R.; McDonagh, A. M.; Humphrey, M. G.; Samoc, M. Organometallic complexes in nonlinear optics I: Second-order nonlinearities. Adv. Organomet. Chem. 1997, 42, 291.
37. Verbiest, T.; Houbrechts, S.; Kauranen, M.; Clays, K.; Persoons, A. Second-order nonlinear optical materials: recent advances in chromophore design. J. Mater. Chem. 1997, 7, 2175.
38. Behrens, U.; Brussaard, H.; Hagenau, U.; Heck, J. Hendrickx, E.; Koernich, J.; van der Linden J. G. M. Persoons, A.; Spek, A. L.; Veldman, N.; Voss, B. Wong, H. Bimetallic sesquifulvalene complexes-compounds with unusually large hyperpolarizability β. Chem. Eur. J. 1996, 2, 98.
39. Houbrechts, S.; Clays, K.; Persoons, A.; Cadierno, V.; Gamaso Pilar, M.; Gimeno, J. Large second-order nonlinear optical properties of novel organometallic σ-arylenynyl ruthenium complexes. Organometallics 1996, 15, 5266.
40. Zyss, J.; Ledoux, I. Nonlinear optics in multipolar media: Theory and experiments. Chem. Rev. 1994, 94, 77.
41. d symmetry. Adv. Mater. 1994, 6, 851.
42. Verbiest, T.; Clays, K.; Samyn, C.; Wolff, J.; Reinhoudt, D.; Persoons, A. Investigations of the hyperpolarizability in organic molecules from dipolar to octopolar systems. J. Am.. Chem. Soc. 1994, 116, 9320.
43. Verbiest, T.; Clays, K.; Persoons, A.; Meyers, F.; Brédas J. L. Determination of the hyperpolarizability of an octopolar molecular ion by HRS. Opt. Lett. 1993, 18, 525.
44. Clays, K.; Hendrickx, E.; Verbiest, T.; Persoons, A. Nonlinear optical properties of correlated chromophores in organic mesoscopic superstructures. Adv. Mater. 1998, 10, 1.
45. Deussen, H. J.; Hendrickx, E.; Boutton, C.; Krog, D.; Clays, K.; Bechgaard, K.; Persoons, A.; Bjornholm, T. Novel chiral bis-dipolar 6,6′-disubstituted binaphthol derivatives for second-order nonlinear optics: Synthesis and linear and nonlinear optical properties. J. Am. Chem. Soc. 1996, 118, 6841.
46. Hendrickx, E.; Boutton, C.; Clays, K.; Persoons, A.; Van Es, S.; Biemans, T.; Meijer, B. Quadratic nonlinear optical properties of correlated chromophores: cyclic 6, 6′-dinitro-1, 1′-binaphthyl-2, 2′-ethers. Chem. Phys. Lett. 1997, 270, 241.
47. Hendrickx, E.; Vinckier, A.; Clays, K.; Persoons, A. Evidence of octopolar symmetry in bacteriorhodopsin by HRS from purple membrane suspensions. J. Phys. Chem. 1996, 100, 19672.
48. Kauranen, M.; Verbiest, T.; Boutton, C.; Teerenstra, M. N.; Clays, K.; Schouten, A. J.; Nolte, R. J. M.; Persoons, A. Supramolecular second-order nonlinearity of polymers with orientationally correlated chromophores. Science 1995, 270, 966.
49. Put, E. H. J.; Clays, K.; Persoons, A.; Biemans, H. A. M.; Luijkx, C. P. M.; Meijer, E. W. The symmetry of functionalized poly(propylene imine) dendrimers probed with HRS. Chem. Phys. Lett. 1996, 260, 136.