Reactions of (chloromethyl)platinum(II) derivatives with nucleophiles. Formation of (dimethylamino)carbene complexes using N,N,N′,N′-tetramethylmethanediamine as nucleophile and the X-ray crystal and molecular structures of cis-[(Ph3P)Pt(CH2NMe3)Cl2]

Organometallics

Volumn 18, Issue 13, 1999, Pages 2428-2439

  Ferguson, George ^a   Li, Yiwei ^a   McAlees, Alan J ^a   McCrindle, Robert ^a   Xiang, Ke ^a  

^a UNIVERSITY OF GUELPH   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000113346     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990049h     Document Type: Article

References (52)

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26. 15
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30. 2Pt(R)X] (L = phosphine). See e.g.: (a) Arnold, D. P.; Bennett, M. A. Inorg. Chem. 1984, 23, 2110-2116. (b) Flood, T. C.; Statler, J. A. Organometallics 1984, 3, 1795-1803. (c) Brainard, R. L.; Miller, T. M.; Whitesides, G. M. Organometallics 1986, 5, 1481-1490. (d) Sen, A.; Chen, J.-T.; Vetter, W. M.; Whittle, R. R. J. Am. Chem. Soc. 1987, 109, 148-156.
31. 2Pt(R)X] (L = phosphine). See e.g.: (a) Arnold, D. P.; Bennett, M. A. Inorg. Chem. 1984, 23, 2110-2116. (b) Flood, T. C.; Statler, J. A. Organometallics 1984, 3, 1795-1803. (c) Brainard, R. L.; Miller, T. M.; Whitesides, G. M. Organometallics 1986, 5, 1481-1490. (d) Sen, A.; Chen, J.-T.; Vetter, W. M.; Whittle, R. R. J. Am. Chem. Soc. 1987, 109, 148-156.
32. 2Pt(R)X] (L = phosphine). See e.g.: (a) Arnold, D. P.; Bennett, M. A. Inorg. Chem. 1984, 23, 2110-2116. (b) Flood, T. C.; Statler, J. A. Organometallics 1984, 3, 1795-1803. (c) Brainard, R. L.; Miller, T. M.; Whitesides, G. M. Organometallics 1986, 5, 1481-1490. (d) Sen, A.; Chen, J.-T.; Vetter, W. M.; Whittle, R. R. J. Am. Chem. Soc. 1987, 109, 148-156.
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38. For recent examples of hydrogen bonds involving four-membered rings, see: Petrucci, M. G. L.; Lebuis, A.-M.; Kakkar, A. K. Organometallics 1998, 17, 4966-4975. For a recent survey of crystal structures involving hydrogen bonds between metal-bound chlorine and hydrogen donors, including H-N groups, see: Aullon, G.; Bellamy, D.; Brammer, L.; Bruton, E. A.; Orpen, A. G. Chem. Commun. 1998, 653-654.
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50. II species formed from certain organoplatinum-amine complexes in the presence of HX. See: (a) Wehman-Ooyevaar, I. C. M.; Grove, D. M.; de Vaal, P.; Dedieu, A.; van Koten, G. Inorg. Chem. 1992, 31, 5484-5493. (b) Wehman-Ooyevaar, I. C. M.; Grove, D. M.; Kooijman, H.; van der Sluis, P.; Spek, A. L.; van Koten, G. J. Am. Chem. Soc. 1992, 114, 9916-9924.
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