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UV-vis absorption spectrum of the supernatant of C6AzSSC12-capped gold particles in hexane (most particles are precipitated) was measured as well, to confirm that the number of the free dyes in solution was negligibly small.
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15/mL. This good agreement of dye numbers implies (1) the reliability of our measurement, and (2) high molecular density on the gold particles.
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Kinetic data of C6AzSSC12 gold nanoparticles taken by shaking the cells, which kept a clear isobestic point until the end of reaction, also perfectly agreed with the data shown in Figure 4.
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Particles synthesized in our laboratory by the Brust method (ref 3) were utilized for the examination.
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