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Volumn 125, Issue 1, 2003, Pages 221-232

Design of novel inorganic-organic hybrid materials based on iron-chloranilate mononuclear complexes: Characteristics of hydrogen-bond-supported layers toward the intercalation of guests

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE; COLUMNS (STRUCTURAL); ELECTROSTATICS; HYDROGEN BONDS; IRON; POSITIVE IONS; SPECTROSCOPY;

EID: 0037425548     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027895v     Document Type: Article
Times cited : (50)

References (85)
  • 32
    • 0004236045 scopus 로고
    • VCH Publishers Inc.: New York
    • Kahn. O. Molecular Magnetism; VCH Publishers Inc.: New York, 1993.
    • (1993) Molecular Magnetism
    • Kahn, O.1
  • 34
    • 0003653434 scopus 로고
    • Oak Ridge National Laboratory: Oak Ridge, TN
    • Johnson, C. K. ORTEP; Report ORNL-5138, Oak Ridge National Laboratory: Oak Ridge, TN, 1976.
    • (1976) ORTEP; Report ORNL-5138
    • Johnson, C.K.1
  • 56
    • 0346772318 scopus 로고    scopus 로고
    • note
    • -1 at 130 K. (Suplementary Figure S9). It behaves as a semiconductor with high activation energy, 0.19 eV.
  • 59
    • 0348033557 scopus 로고    scopus 로고
    • note
    • The temperature dependence of the recoil-free fraction. ln[A/A(78)] of 1 (Supplementary, Figure S7) shows a nonlinearity above 250 K indicative of the existence of a phase transition. This situation is well supported by the DSC traces of 1, which shows one thermal anomaly at 270 K (Supplementary, Figure S8). The origin of the phase transition is not clear at this stage. However, protons of water molecules may moderate the phase transition and cause the inflection of Mössbauer spectral intensities at around 250 K through hydrogen-bonding interaction.
  • 85
    • 0347402679 scopus 로고    scopus 로고
    • note
    • 3 + 1.92813α4.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.