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The indirect interaction which may occur in molecular systems differs from that occurring in the inorganic classical metals in the following points: (1) Most often the interaction between localized and conduction electrons is intermolecular, and thus weak, and involves a d-π exchange interaction, while in the inorganic metals this interaction is intra-atomic, and thus quite strong, and involves a direct interaction between localized 3d or 4f electrons and the delocalized conduction electrons (which are mainly of s character). (2) The electron correlation effects are much more important in the molecular metals than in the inorganic ones, and, therefore, the RKKY free electron model may be a too rude approach to account for the indirect exchange interactions in these hybrid molecular materials.
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66
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2642654336
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note
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1 phase (notice that the centrosymmetric dimers may only have three different relative positions in the stack).
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-
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67
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2642628804
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note
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1 structure (see ref 18), whereas that with the [PW12] anion presents a completely different structure and stoichiometry (3:1) (see ref 14b).
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-
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68
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0001305809
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Torrance, J. A.; Scot, B. A.; Welber, F. B. Phys. Rev B 1979, 19, 730.
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Torrance, J.A.1
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69
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0000299889
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The assignment have been made following the nomenclature of (a) Swietlik, R.; Garrigou-Lagrange, C.; Sourisseau, C.; Pages, G.; Delhaes, P. J. Mater. Chem. 1992, 2, 857, with the interpretations of (b) Maceno, G. Ph.D. Thesis, Bordeaux, France, 1988 and (c) Kozlov, M. E.; Pokhodnia, K. I.; Yurchenko, A. A. Spectrochim. Acta 1989, 45A, 437.
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Swietlik, R.1
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Pages, G.4
Delhaes, P.5
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70
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0000299889
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Ph.D. Thesis, Bordeaux, France
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The assignment have been made following the nomenclature of (a) Swietlik, R.; Garrigou-Lagrange, C.; Sourisseau, C.; Pages, G.; Delhaes, P. J. Mater. Chem. 1992, 2, 857, with the interpretations of (b) Maceno, G. Ph.D. Thesis, Bordeaux, France, 1988 and (c) Kozlov, M. E.; Pokhodnia, K. I.; Yurchenko, A. A. Spectrochim. Acta 1989, 45A, 437.
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Maceno, G.1
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71
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0000861914
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The assignment have been made following the nomenclature of (a) Swietlik, R.; Garrigou-Lagrange, C.; Sourisseau, C.; Pages, G.; Delhaes, P. J. Mater. Chem. 1992, 2, 857, with the interpretations of (b) Maceno, G. Ph.D. Thesis, Bordeaux, France, 1988 and (c) Kozlov, M. E.; Pokhodnia, K. I.; Yurchenko, A. A. Spectrochim. Acta 1989, 45A, 437.
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Kozlov, M.E.1
Pokhodnia, K.I.2
Yurchenko, A.A.3
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0027660333
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Moldenhauer, J.; Horn, Ch.; Pokhodnia, K. I.; Schweitzer, D.; Heinen, I.; Keller, H. J. Synth. Met. 1993, 60, 31.
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Moldenhauer, J.1
Horn, Ch.2
Pokhodnia, K.I.3
Schweitzer, D.4
Heinen, I.5
Keller, H.J.6
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73
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2642599114
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note
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Owing to the small size of the crystals, conductivity measurements were performed using a two-probe method.
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74
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2642692797
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Ph.D. Thesis, Bordeaux, France
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(a) Laversanne, R. Ph.D. Thesis, Bordeaux, France, 1987.
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Laversanne, R.1
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(b) Obertelli, S. D.; Friend, R. H.; Talham, D. R.; Kurmoo, M.; Day, P. J. Phys.: Condens. Matter 1989, 1, 5671.
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Obertelli, S.D.1
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Day, P.5
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76
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2642595159
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note
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III ions: see ref 8.
-
-
-
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77
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-
2642597183
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-
note
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+ or ET). Thus, the structure of the nickel containing ET salt will be used to get information on the distortions of the Z site in the monosubstituted Keggin anions.
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-
-
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80
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33845553529
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(b) Sánchez, C.; Livage, J.; Launay, J. P.; Fournier, M.; Jeannin, Y. J. Am. Chem. Soc. 1982, 104, 3194.
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Jeannin, Y.5
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82
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Gatteschi, D.1
Sessoli, R.2
Plass, W.3
Müller, A.4
Krickemeyer, E.5
Meyer, J.6
Sölter, D.7
Adler, P.8
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84
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0003304202
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Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: The Netherlands
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(b) Casañ-Pastor, N.; Baker, L. C. W. In Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: The Netherlands, 1994; p 203.
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Casañ-Pastor, N.1
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