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Volumn 121, Issue 46, 1999, Pages 10743-10746

Assembly of metal-anion arrays within a perovskite host. Low-temperature synthesis of new layered copper-oxyhalides, (CuX)LaNb2O7, X = Cl, Br

Author keywords

[No Author keywords available]

Indexed keywords

BROMINE; CHLORIDE; COPPER COMPLEX; HALIDE;

EID: 0033601085     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991566u     Document Type: Article
Times cited : (109)

References (38)
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    • See for example: (a) Sato, M.; Abo, J.; Jin, T.; Ohta, M. Solid State Ionics 1992, 51, 85. (b) Sato, M.; Abo, J.; Jin, T. Solid State Ionics 1992, 57, 285. (c) Sato, M.; Abo, J.; Jin, T.; Ohta, M. J. Alloys Compd. 1993, 81. (d) Sato, M.; Jin, T.; Ueda, H. Chem. Lett. 1994, 161.
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    • note
    • These reactions are carried out below the decomposition/melting points of the copper halides and of the rabidium-halide byproducts. It is possible that a eutectic may form between the copper and rubidium halides to assist in the diffusion process, otherwise these reactions likely proceed by solid-state diffusion of the ions.
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    • note
    • 33 values of 0.166, 0.166, and 0.063, and 0.101, 0.101, and 0.048, respectively.
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    • note
    • wp, respectively.
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    • 10.


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