A highly regio-, diastereo- and enantioselective intramolecular cyclopropanation reaction of a racemic α-diazo ketone catalyzed by chiral ortho-metalated dirhodium(II) compounds

Tetrahedron Asymmetry

Volumn 14, Issue 7, 2003, Pages 787-790

  Pérez Prieto, Julia ^a   Stiriba, Salah Eddine ^a   Moreno, Eduardo ^a   Lahuerta, Pascual ^a  

^a UNIVERSITY OF VALENCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

1 DIAZO 6 METHYL 3 (2 PROPENYL) 5 HEPTEN 2 ONE; ALPHA DIAZO KETONE; KETONE DERIVATIVE; PHOSPHINE DERIVATIVE; RHODIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CYCLOPROPANATION; ENANTIOMER; ENANTIOSELECTIVITY; EXPERIMENTAL TEST; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; STEREOISOMERISM;

EID: 0037418798     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(02)00870-4     Document Type: Article

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25. 2: C, 58.76; H, 4.23; N, 2.45. Found: C, 57.86; H, 4.60; N, 2.36%.