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Volumn 21, Issue 8, 2002, Pages 1667-1673

Chiral dirhodium(II) catalysts with ortho-metalated arylphosphine ligands: Synthesis and application to the enantioselective cyclopropanation of α-diazo ketones

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; KETONES; SOLVENTS; SUBSTRATES; SYNTHESIS (CHEMICAL);

EID: 0001695571     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0110437     Document Type: Article
Times cited : (58)

References (46)
  • 2
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    • Rappoport, Z., Ed.; Wiley: Chichester, U.K.; Chapter 8
    • (b) Reissig, H. U. In The Chemistry of the Cyclopropyl Group; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 1987; Chapter 8, p 375.
    • (1987) The Chemistry of the Cyclopropyl Group , pp. 375
    • Reissig, H.U.1
  • 4
    • 0001403071 scopus 로고    scopus 로고
    • Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, Chapter 16.1
    • (a) Pfaltz, A. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Vol. II, Chapter 16.1, p 513.
    • (1999) Comprehensive Asymmetric Catalysis , vol.2 , pp. 513
    • Pfaltz, A.1
  • 5
    • 0001403071 scopus 로고    scopus 로고
    • Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, Chapter 16.2
    • (b) Lydon, K. M.; McKervey, M. A. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Vol. II, Chapter 16.2, p 539.
    • (1999) Comprehensive Asymmetric Catalysis , vol.2 , pp. 539
    • Lydon, K.M.1    McKervey, M.A.2
  • 6
    • 0000531610 scopus 로고    scopus 로고
    • Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, Chapter 16.3
    • (c) Charette, A. B.; Lebel, H. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Vol. II, Chapter 16.3, p 581.
    • (1999) Comprehensive Asymmetric Catalysis , vol.2 , pp. 581
    • Charette, A.B.1    Lebel, H.2
  • 7
    • 0001691372 scopus 로고    scopus 로고
    • Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, Chapter 41.3
    • (d) Aratani, T. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Vol. III, Chapter 41.3. p 1451.
    • (1999) Comprehensive Asymmetric Catalysis , vol.3 , pp. 1451
    • Aratani, T.1
  • 23
    • 0000831883 scopus 로고
    • Rabjohn, N., Ed.; Wiley: New York
    • Boer, Th.; Backer, H. J. In Organic Synthesis; Rabjohn, N., Ed.; Wiley: New York, 1963; Vol. IV, p 250.
    • (1963) Organic Synthesis , vol.4 , pp. 250
    • Boer, Th.1    Backer, H.J.2
  • 24
    • 0030796786 scopus 로고    scopus 로고
    • Usually, the enantioselectivity increases by lowering the reaction temperature: (a) Davies, H. M. L.; Hansen, T. J. Am. Chem. Soc. 1997, 119, 9075.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 9075
    • Davies, H.M.L.1    Hansen, T.2
  • 33
    • 0038023717 scopus 로고    scopus 로고
    • note
    • 17f
  • 36
    • 84981828672 scopus 로고
    • It should be noted that cyclopentanones 23 and 27, obtained from the same rhodium enantiomer, have different spatial configurations. However, the absolute configurations assigned to them are the same, due to the priority rules of the groups around the stereocenters: (a) Cahn, R. S.; Ingold, C. K.; Prelog, V. Angew. Chem., Int. Ed. Engl. 1966, 5, 385.
    • (1966) Angew. Chem., Int. Ed. Engl. , vol.5 , pp. 385
    • Cahn, R.S.1    Ingold, C.K.2    Prelog, V.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.