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5 ring makes an angle of ca. 70° with the five atoms of the coordination plane, and, as in 3a, there is a tetrahedral distortion, albeit a smaller one: P1(ca. -0.06 Å) and I1(ca. -0.06 Å) are slightly below, and P2(ca. 0.03 Å) and C1L-(ca. 0.04 Å), slightly above the coordination plane. The Pd-C1L, 2.062-(3) Å, and Pd-I1, 2.6284(3) Å, separations are as expected. In contrast to 3a the coordination angles in 3b do not deviate markedly from those expected for a slightly distorted square planar geometry. The P-Pd-P angle is ca. 93°.
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