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Volumn 18, Issue 4, 1999, Pages 670-678

Contributions to the enantioselective Heck reaction using MeO-Biphep ligands. The case against dibenzylidene acetone

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Indexed keywords


EID: 0001241279     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980783l     Document Type: Article
Times cited : (73)

References (65)
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    • note
    • A similar approach to generating Pd(0) in solution is given by Amatore and co-workers in ref 17b.
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    • note
    • 2; however both react on the seconds time scale, so that our NMR measurements were not quick enough to make this distinction.
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    • note
    • 5 ring makes an angle of ca. 70° with the five atoms of the coordination plane, and, as in 3a, there is a tetrahedral distortion, albeit a smaller one: P1(ca. -0.06 Å) and I1(ca. -0.06 Å) are slightly below, and P2(ca. 0.03 Å) and C1L-(ca. 0.04 Å), slightly above the coordination plane. The Pd-C1L, 2.062-(3) Å, and Pd-I1, 2.6284(3) Å, separations are as expected. In contrast to 3a the coordination angles in 3b do not deviate markedly from those expected for a slightly distorted square planar geometry. The P-Pd-P angle is ca. 93°.
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