Molybdenum and tungsten structural analogues of the active sites of the MoIV + [O] → MoVIO oxygen atom transfer couple of DMSO reductases

Journal of the American Chemical Society

Volumn 120, Issue 13, 1998, Pages 3259-3260

  Donahue, James P ^a   Lorber, Christian ^a,b   Nordlander, Ebbe ^b   Holm, R H ^a  

^a HARVARD UNIVERSITY   (United States)

^b LUND UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000078858     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja973917f     Document Type: Letter

References (38)

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5. 2 are unclear, but may relate to the conditions of crystallization.
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26. -1.
27. max (SM) 301 (10 500), 352 (22 200), 388 (sh), 461 (sh), 570 (265) nm.
28. -1.
29. -1
30. M) 307 (21 100), 345 (6740), 420 (420), 553 (85) nm.
31. -).
32. M) 296 (14 300), 325 (sh), 340 (sh), 375 (sh), 456 (3720), 600 (1610) nm.
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34. 2) = 2.29(5.46)%.
35. 2) = 3.67(7.31)%. Data were collected with Mo Kα radiation, and structures were solved by direct methods and refined by standard procedures; absorption corrections were applied to all data sets.
36. 10,13 for which the differences are ∼0.04 Å.
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38. (g).