Synthesis and solution self-assembly of coil-crystalline-coil polyferrocenylphosphine-b-polyferrocenylsilane-b-polysiloxane triblock copolymers

Macromolecules

Volumn 35, Issue 24, 2002, Pages 9146-9150

  Wang, Xiao Song ^a   Winnik, Mitchell A ^a   Manners, Ian ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

POLYDISPERSITY;

ANIONIC POLYMERIZATION; CRYSTALLIZATION; MICELLES; ORGANOMETALLICS; RING OPENING POLYMERIZATION; SELF ASSEMBLY; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

BLOCK COPOLYMERS;

EID: 0037137404     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma020564i     Document Type: Article

References (29)

1. Hamley, I.W. The Physics of Block Copolymers; Oxford University Press: New York, 1998.
2. (a) Forster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195.
3. (b) Simon, P.W.; Ulrich, R.; Spiess, H.W.; Wiesner, U. Chem. Mater. 2001, 13, 3464.
4. (c) Zhang, L.F.; Eisenberg, A. Science 1995, 268, 1728.
5. (d) Zhang, L.F.; Eisenberg, A. J. Am. Chem. Soc. 1996, 118, 3168.
6. (e) Liu, G.J. Curr. Opin. Colloid Interface Sci. 1998, 3, 200.
7. (f) Wilhelm, M.; Zhao, C.L.; Wang, Y.C.; Xu, R.L.; Winnik, M.A.; Mura, J.L.; Riess, G.; Croucher, M.D. Macromolecules 1991, 24, 1033.
8. (a) Manners, I. Science 2001, 294, 1664.
9. (b) Hou, S.J.; Chan, W.K. Macromol. Rapid Commun. 1999, 20, 440.
10. (c) Fraser, C.L.; Smith, A.P.; Wu, X.F. J. Am. Chem. Soc. 2000, 122, 9026.
11. (d) Goby, J.-F.; Lohmeijer, B.G.G.; Schubert, U.S. Macromolecules 2002, 35, 4560.
12. (a) Rulkens, R.; Ni, Y.; Manners, I. J. Am. Chem. Soc. 1994, 116, 12121.
13. (b) Ni, Y.; Rulkens, R.; Manners, I. J. Am. Chem. Soc. 1996, 118, 4102.
14. (c) Honeyman, C.H.; Peckham, T.J.; Massey, J.A.; Manners, I. Chem. Commun. 1996, 2589.
15. (d) Peckham, T.J.; Massey, J.A.; Honeyman, C.H.; Manners, I. Macromolecules 1999, 32, 2830.
16. Massey, J.A.; Power, K.N.; Winnik, M.A.; Manners, I. Adv. Mater. 1998, 10, 1559.
17. Massey, J.A.; Power, K.N.; Manners, I.; Winnik, M.A. J. Am. Chem. Soc. 1998, 120, 9533.
18. Kulbaba, K.; Manners, I. Macromol. Rapid Commun. 2001, 22, 711.
19. MacLachlan, M.J.; Ginzburg, M.; Coombs, N.; Coyle, T.W.; Raju, N.; Greedan, J.E.; Ozin, G.A.; Manners, I. Science 2000, 287, 1460.
20. Massey, J.A.; Winnik, M.A.; Manners, I.; Chan, V.Z.-H.; Ostermann, J.M.; Enchelmaier, R.; Spatz, J.P.; Möller, M. J. Am. Chem. Soc. 2001, 123, 3147.
21. Massey, J.A.; Temple, K.; Cao, L.; Rharbi, Y.; Raez, J.; Winnik, M.A.; Manners, I. J. Am. Chem. Soc. 2000, 122, 11577.
22. (a) Resendes, R.; Massey, J.; Dorn, H.; Power, K.N.; Winnik, M.A.; Manners, I. Angew. Chem., Int. Ed. 1999, 38, 2570.
23. (b) Resendes, R.; Massey, J.A.; Temple, K.; Cao, L.; Power-Billard, K.N.; Winnik, M.A.; Manners, I. Chem.-Eur. J. 2001, 7, 2414.
24. For work on the crystallization of PFS homopolymer see: (a) Rasburn, J.; Petersen, R.; Jahr, T.; Rulkens, R.; Manners, I.; Vancso, G. J. Chem. Mater. 1995, 7, 871.
25. (b) Rulkens, R.; Lough, A.J.; Manners, I.; Lovelace, S.R.; Grant, C.; Geiger, W.E. J. Am. Chem. Soc. 1996, 118, 12683.
26. (c) Papkov, V.S.; Gerasimov, M.V.; Dubovik, I.I.; Sharma, S.; Dementiev, V.V.; Pannell, K.H. Macromolecules 2000, 33, 7107.
27. (d) Chen, Z.; Foster, M.D.; Zhou, W.; Fong, H.; Reneker, D.H.; Resendes, R.; Manners, I. Macromolecules 2001, 34, 6156.
28. Although the PFS:PDMS block ratio (1:12) is larger in this case compared to the other samples (1:5-1:8) we note that asymmetric crystalline-coil PFS-b-PDMS diblock copolymers with block ratios of up to 1:18 also form cylindrical structures in n-hexanes but in these cases the structures are tubular. See: (a) Raez, J.; Manners, I.; Winnik, M.A. J. Am. Chem. Soc. 2002, 124, 10381.
29. Raez, J.; Manners I.; Winnik, M.A. Langmuir 2002, 18, 7229.