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Volumn 106, Issue 41, 2002, Pages 9407-9419

Solvatochromism and solvation dynamics of structurally related cyanine dyes

Author keywords

[No Author keywords available]

Indexed keywords

MAGIC ANGLE PUMP; SOLVATION DYNAMICS; SOLVATOCHROMISM; TRICARBOCYANINE DYES;

EID: 0037126445     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0205867     Document Type: Article
Times cited : (90)

References (107)
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    • note
    • This discussion ignores coupling between the orientational and electronic polarization. This is justified if an enhanced electronic polarization arises through the orientational polarization as in Onsager's reaction field because this will relax with the orientational polarization. It has been argued that a large orientational polarization suppresses the electronic polarization, and another ad hoc separation has been proposed. Brady, J. E.; Carr, P. W. J. Phys. Chem. 1985, 89, 5759-5766.
    • (1985) J. Phys. Chem. , vol.89 , pp. 5759-5766
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    • 3 implies either a solute refractive index n = 2 or a cavity volume less than the volume per molecule of the solute condensed phase (for n < 2).
    • (1985) J. Phys. Chem. , vol.89 , pp. 4181-4188
    • Van Der Zwan, G.1    Hynes, J.T.2
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    • M.S. Thesis, University of Colorado, Boulder
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    • (2000)
    • Tolbert, C.A.1
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    • note
    • This conductance meter did not allow measurements at sufficiently low concentration to determine the limiting molar conductivity at zero concentration. The apparent molar conductivity was determined from the change in conductivity divided by the total dye concentration. All of the neat solvents exceeded the literature conductivity, probably due to impurities.
  • 66
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    • CRC Press Inc.: Boca Raton, FL; (Refractive indices were taken from the tabulation of "physical constants of organic compounds".)
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    • (1988) CRC Handbook of Chemistry and Physics, 1st Student Ed.
    • Weast, R.C.1
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    • -) is the radius of the cation (anion). Atkins, P. Physical Chemistry, 5th ed.; W. H. Freeman and Company: New York, 1994.
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    • Atkins, P.1
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    • 0002940117 scopus 로고
    • note
    • TGII(T) = exp-(-T/L)[1 + 2r(T)], where the anisotropy r(T) = (2/5) exp(-T/R) for a nondegenerate two-level system. This is a special case (β/α = 4/5) of the expression used by: Phillion, D. W.; Kuizenga, D. J.; Siegman, A. E. Appl. Phys. Lett. 1975, 27, 85-87.
    • (1975) Appl. Phys. Lett. , vol.27 , pp. 85-87
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    • Haroche, S.1
  • 99
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    • note
    • j for modes i and j that can generate an effectively inhomogeneous distribution of vibrational frequencies for mode i due to a thermal distribution of quantum numbers for mode j.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.